MCQ
Two H atoms in the ground state collide inelastically. The maximum amount by which their combined kinetic energy is reduced is:
  • A
    10.20eV.
  • B
    20.40eV.
  • C
    13.6eV.
  • D
    27.2eV.

Answer

  1. 10.20eV.

Solution:

Key concept: Total energy (E) is the sum of potential energy and kinetic energy, i.e. E = K + U

$\Rightarrow\ \text{E}=-\frac{\text{kZe}^2}{2\text{r}_\text{n}}\text{also r}_\text{n}=\frac{\text{n}^2\text{h}^2\in_0}{\pi\text{mze}^2}$

Hence $\text{E}=-\bigg(\frac{\text{me}^4}{8\in_0^2\text{h}^2}\bigg)\frac{\text{Z}^2}{\text{n}^2}=-\bigg(\frac{\text{me}^4}{8\in_0^2\text{ch}^3}\bigg)\text{ch}\frac{\text{Z}^2}{\text{n}^2}$

$=-\text{R ch}\frac{\text{Z}^2}{\text{n}^2}=-13.6\frac{\text{Z}^2}{\text{n}^2}\text{eV}$

The lowest state of the atom, called the ground state, is that of the lowest energy. The energy of this state (n = 1), E1 is -13.6eV

Energy level diagram of hydrogen/hydrogen like atom:

Principal quantum number Orbit Excited state Energy of H2 - atom
$\text{n}=\infty$
Infinite Infinite 0eV
n = 4 Fourth Third -0.85eV
n = 3 Third Second -1.51eV
n = 2 Second First -3.4eV
n = 1 First Ground -13.6eV

Let two H atoms initially at in the ground state.Now two stoms collide inclastically. The total energy associated with the tow H-atoms

= 2 × (13.6 eV) = 27.2eV

The maximum amount by which their combined kinetic energy is reduced when any one of them goes into first excited state (n = 2) after the inclastic collision.

The total energy associated with the two H-atoms after the collision

$=\Big(\frac{13.6}{2^2}\Big)+(13.6)=17.0\text{eV}$

Hence, maximum loss of their combined kinetic energy

= 27.2 - 17.0 = 10.2eV.

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