ઊંચ્ચ સ્પીન $d^4$ અષ્ટફલકીય સંકીર્ણ માટે સ્ફટીક ક્ષેત્ર ઊર્જા .............. છે ?
A$- 1.2 \Delta _o$
B$- 0.6 \Delta _o$
C$- 0.8 \Delta _o$
D$- 1.6 \Delta _o$
NEET 2013, Diffcult
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b n the case of high spin complex \(\Delta_{0}\) is small. Thus, the energy required to pair up the fourth electron with the electrons of lower energy \(d-\)orbitals would be higher than that required to place the electrons in the higher \(d-\)orbital. Thus pairing does not occur.
For high spin \(d^4\) octahedral complex,
therefore, Crystal field stabilisation energy
\(=(-3 \times 0.4+1 \times 0.6) \Delta_{0}\)
\(=-(-1.2 \times 0.6) \Delta_{0}\)
\(=-0.6\Delta_{0}\)
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