MCQ
When chloroform is treated with amine and $KOH,$ we get
- ARose odour smell
- BSour almond like smell
- ✓Offensive odour
- DSour oil of winter green like smell
$\mathop {{C_2}{H_5} - N\vec = C + }\limits_{{\text{Ethylisocyanide(offensive odour)}}} 3KCl + 3{H_2}O$
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$O(g) + e^- = O^-(g)$ $\Delta {H_{eg}} = - 142\,kJ\,mo{l^{ - 1}}$
$O^-(g) + e^- = O^{2-}(g)$ $\Delta {H_{eg}} = +844\,kJ\,mo{l^{ - 1}}$
This is because
$\begin{align}
\begin{matrix}
O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
H-O-C-C{{H}_{2}}-C{{H}_{2}}-CH-C{{O}_{2}}H \\
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,| \\
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\underset{\oplus }{\mathop{N}}\,{{H}_{3}} \\
\end{matrix}\,\,\,\,\,(p{{K}_{a}}=2) \\
(p{{K}_{a}}=4)\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,(p{{K}_{a}}=9) \\
\end{align}$