MCQ
Which of following is phenolic
  • A
    Phthalic acid
  • B
    Phosphoric acid
  • Picric acid
  • D
    Phenylacetic acid

Answer

Correct option: C.
Picric acid
c
(c) Picric acid is phenolic whileothers are non phenolic.

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Given: Freezing point depression constant of water $\left(\mathrm{K}_{\mathrm{f}}^{\text {rate }}\right)=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$

Freezing point depression constant of ethanol $\left(\mathrm{K}_{\mathrm{f}}^{\text {ethunol }}\right)=2.0 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$

Boiling point elevation constant of water $\left(\mathrm{K}_{\mathrm{b}}^{\text {nate }}\right)=0.52 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$

Boiling point elevation constant of ethanol $\left(\mathrm{K}_{\mathrm{b}}^{\text {ethanol }}\right)=1.2 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$

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Standard freezing point of ethanol $=155.7 \mathrm{~K}$

Standard boiling point of water $=373 \mathrm{~K}$

Standard boiling point of ethanol $=351.5 \mathrm{~K}$

Vapour pressure of pure water $=32.8 \mathrm{~mm} \mathrm{Hg}$

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Molecular weight of water $=18 \mathrm{~g} \mathrm{~mol}^{-1}$

Molecular weight of ethanol $=46 \mathrm{~g} \mathrm{~mol}^{-1}$

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$(C)$ $29.5 \mathrm{~mm} \mathrm{Hg}$ $(D)$ $28.8 \mathrm{~mm} \mathrm{Hg}$

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$(A)$ $380.4 \mathrm{~K}$ $(B)$ $376.2 \mathrm{~K}$

$(C)$ $375.5 \mathrm{~K}$ $(D)$ $354.7 \mathrm{~K}$

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