- AWater + ethanol
- BChloroform + carbon tetrachloride
- ✓Benzene + toluene
- DWater + hydrochloric acid
Chloroform $+$ carbon tetrachloride show positive deviation from Raoult's law Water $+ HCl$ is a non-ideal solution showing negative deviations from Raoult's law.
In a Benzene-toluene mixture, $A - B$ interactions are almost equal to $A - A$ and $B -B$ interactions due to the very small difference in the two compounds, i.e., they differ just by one $CH_2$ group. Hence, no deviation will occur from Raoult's law.
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$(I)$ ${O_3} \to $ product
$(II)$ $C{r_2}O_7^{2 - }\xrightarrow{{{H^ + }}}$ product
$(III)$ $MnO_4^\Theta \xrightarrow{{{H^ + }}}$ product
$(IV)$ $H_2S \longrightarrow $ product

( $p$ : pressure, $V$ : volume, $T$ : temperature, $H$ : enthalpy, $S$ : entropy)
$SF _{4}, BF _{4}^{-}, CIF _{3}, AsF _{3}, PCl _{5}, BrF _{5}, XeF _{4}, SF _{6}$