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Reason : Oxygen forms $p\pi \,-\, p\pi $ multiple bond due to small size and small bond length but $p\pi \,-\,p\pi $ bonding is not possible in sulphur.
$(I)$ $\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right] \mathrm{Br}_{2}$
$(II)$ $ \mathrm{Na}_{4}\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]$
$(III)$ $\mathrm{Na}_{3}\left[\mathrm{Fe}\left(\mathrm{C}_{2} \mathrm{O}_{4}\right)_{3}\right]\left(\Delta_{0}>\mathrm{P}\right)$
$(IV)$ $\left(\mathrm{Et}_{4} \mathrm{N}\right)_{2}\left[\mathrm{CoCl}_{4}\right]$
$\,\begin{array}{*{20}{c}}
{C{H_3} - CH - C{H_2} - CH - C{H_2} - C{H_3}}\\
{\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}\\
{\,\,\,\,\,\,\,\,\,Br\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,Br\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array}$ $\xrightarrow[{heat}]{{KOH,\,C{H_3}OH}}$
$2H_2 + 2NO \to N_2 + 2H_2O$
the following mechanism has been proposed
$(i)$ $2NO \rightleftharpoons N_2O_2\,$ (fast)
$(ii)$ $N_2O_2 + H_2 \xrightarrow{{{k_2}}} N_2O + H_2O\,$ (slow)
$(iii)$ $N_2O + H_2 \to N_2 + H_2O\,$ (fast)
then what will be the rate law of this reaction ?