Question
Which of the following will give $Fe^{3+}$ ions in the solution?

Answer

$\ce{[Fe(CN)_6​]^{3−}}$ and $\ce{[Fe(CN)_6​]^{4−}}$​ are complex ions.They retain their identity in the solution.
Hence, they will not give $Fe^{3+}$ ions in the solution.
$\ce{NH_4​(SO_4​)_2​.FeSO_4​.6H_2​O}$ is a double salt.
In the solution, it breaks into individual ions, but it will give $Fe^{2+}$ ions in the solution.
Similarly, $\ce{Fe_2​(SO_4​)_{3​}​}$ also breaks into individual ions.
Hence, they will give $Fe^{3+}$ ions in the solution.

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