MCQ
Which one of the following hydrides is least stable
  • A
    $As{H_3}$
  • $Sb{H_3}$
  • C
    $N{H_3}$
  • D
    $P{H_3}$

Answer

Correct option: B.
$Sb{H_3}$
b
(b) $\xrightarrow{{N{H_3}\,\, > \,\,\,P{H_3}\,\,\, > As{H_3}\,\, > \,\,Sb{H_3}\, > \,\,\,Bi{H_3}_{}}}$

Stability decreases down the group because bond energy decreases down the group.

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$\begin{array}{*{20}{c}}
  {C{H_3} - CH = CH - CH - CH - C{H_3}} \\ 
  {{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{\mkern 1mu} {\mkern 1mu} |{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,\,\,\,\,\,\,\,\,\,{\mkern 1mu} {\mkern 1mu} |{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} } \\ 
  {\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,OH{\mkern 1mu} {\mkern 1mu} {\mkern 1mu} {\mkern 1mu} \,\,\,\,{\mkern 1mu} {\mkern 1mu} \,\,\,{\mkern 1mu} {\mkern 1mu} OH\,\,} 
\end{array}\,$

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