MCQ
Which statement is wrong
  • A
    Two products are formed in this reaction
  • B
    This reaction is an example of anti-addition reaction
  • This reaction has cyclic bromonium ion intermediate
  • D
    The formed products will have enantiomeric relationship

Answer

Correct option: C.
This reaction has cyclic bromonium ion intermediate
c

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Combustion of $1$ mole of benzene is expressed at

$\mathrm{C}_6 \mathrm{H}_6(1)+\frac{15}{2} \mathrm{O}_2(\mathrm{~g}) \rightarrow \mathrm{CO}_2(\mathrm{~g})+3 \mathrm{H}_2 \mathrm{O}(1) \text {. }$

The standard enthalpy of combustion of $2 \mathrm{~mol}$ of benzene is - ' $x$ ' $k J$.

$\mathrm{x}=$. . . . . . . . . .

$(1)$ standard Enthalpy of formation of $1 \mathrm{~mol}$ of $\mathrm{C}_6 \mathrm{H}_6(1)$, for the reaction $6 \mathrm{C}$ (graphite) $+3 \mathrm{H}_2(\mathrm{~g}) \rightarrow \mathrm{C}_6 \mathrm{H}_n(1)$ is $48.5 \mathrm{~kJ} \mathrm{~mol}^{-1}$.

$(2)$ Standard Enthalpy of formation of $1 \mathrm{~mol}$ of $\mathrm{CO}_2(\mathrm{~g})$, for the reaction $\mathrm{C}$ (graphite) $+\mathrm{O}_{2(\mathrm{~g})} \rightarrow \mathrm{CO}_2(\mathrm{~g})$ is $-393.5 \mathrm{~kJ} \mathrm{~mol}^{-1}$.

$(3)$ Standard and Enthalpy of formation of $1 \mathrm{~mol}$ of $\mathrm{H}_2 \mathrm{O}(1)$, for the reaction $\mathrm{H}_2(\mathrm{~g})+\frac{1}{2} \mathrm{O}_2(\mathrm{~g}) \rightarrow \mathrm{H}_2 \mathrm{O}(1)$ is $-286 \mathrm{~kJ} \mathrm{~mol}^{-1}$.

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