Question
Why the group 17 (halogen) elements of periodic table have more negative value of electron gain enthalpy?

Answer

The following reasons are responsible for the more negative value of electron gain enthalpy of group 17 elements : (i) Small atomic size (ii) More effective nuclear charge (iii) $ns ^2 np ^5$ configuration.
Hence their electron gaining tendency is more and they accept an electron and gain the stable electronic configuration $\left( ns ^2 np ^6\right)$ like noble gases.

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