CCl4 and water are immiscible whereas ethanol and water are miscible in all proportions. Correlate this behaviour with molecular structure of these compounds.CCl4 is a non-polar covalent compound, whereas water is a polar compound. CCl4 can neither form hydrogen bonds with water molecules nor can it break hydrogen bonds between water molecule, therefore, it is insoluble in water. Ethanol is a polar compound and can form hydrogen bonds with water, which is a polar solvent, therefore it is miscible with water in all proportions.