Question
Write two applications of electrochemical series.

Answer

Applications of electrochemical series:
  • The relative strength of reducing agents:
  1. The species on the right side of half-reactions are reducing agents.
  2. The species appearing at the bottom right side of half-reactions associated with large negative E° values are the effective electron donors. They serve as strong reducing agents.
  3. The strength of reducing agents increases from top to bottom as E° values decrease.
  • Spontaneity of redox reactions:
  1. Spontaneity of redox reactions can be predicted from values of electrode potential in electrochemical series.
  2. If the species with a higher E° value is reduced (accepts electrons) and that with a lower E° value is oxidized (donates electrons), then the redox reaction in a galvanic cells is spontaneous.
  3. The standard cell potential must be positive for a cell reaction to be spontaneous under the standard conditions.

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