Question types

The d- and f-Block Elements question types

140 questions across 7 question groups — pick any mix to generate a Chemistry paper with step-by-step answer keys.

140
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Sample Questions

The d- and f-Block Elements questions

One sample from each question group in this chapter. Select any group above to see the full set with answer keys.

Name the oxometal anions of the first series of the transition metals in which the metal exhibits the oxidation state equal to its group number.
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Which is the last element in the series of the actinoids? Write the electronic configuration of this element. Comment on the possible oxidation state of this element.
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Q 213 Marks Question3 Marks
Write down the number of 3d electrons in each of the following ions :
$Ti ^{2+}, V ^{2+}, Cr ^{3+}, Mn ^{2+}, Fe ^{2+}, Fe ^{3+}, Co ^{2+}, Ni ^{2+}, Cu ^{2+}$.
Indicate how would you expect the five 3d orbitals to be occupied for these hydrated ions (octahedral).
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Q 223 Marks Question3 Marks
For M2+/M and M3+/M2+ systems the $E ^{\circ}$ values for some metals are as follows : 
$\begin{array}{llll} Cr ^{2+} / Cr & -0.9 V & Cr ^3 / Cr ^{2+} & -0.4 V \\ Mn ^{2+} / Mn & -1.2 V & Mn ^{3+} / Mn ^{2+} & +1.5 V \\ Fe ^{2+} / Fe & -0.4 V & Fe ^{3+} / Fe ^{2+} & +0.8 V\end{array}$
Use this data to comment upon :
(i) the stability of Fe3+ in acid solution are compared to that of Cr3+or Mn3+ and
(ii) the case with which iron can be oxidised as compared to a similar process for either chromium or manganese metal.
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Q 233 Marks Question3 Marks
Describe the oxidising action of potassium dichromate and write the ionic equation for its reaction with : 
(i) Iodide, (ii) Iron, (II) solution and (iii) H2S
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Q 243 Marks Question3 Marks
Describe the preparation of potassium dichromate from iron chromite ore. What is the effect of increasing pH on a solution of potassium dichromate?
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Q 253 Marks Question3 Marks
Permanganate ion $\left( MnO _4^{-}\right)$gives different reduction products at different concentration of hydrogen ions, write their equations.
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What can be inferred from the magnetic moment values of the following complex species?
ExampleMagnetic Moment (BM)
$K _4\left[ Mn ( CN )_6\right]$2.2
$\left[ Fe \left( H _2 O \right)_6\right]^{2+}$5.3
$K _2\left[ MnCl _4\right]$5.9
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Comment on the statement that elements of the first transition series possess many properties different from those of heavier transition elements.
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Compare the general characteristics of the first series of the transition metals with those of the second and third series metals in the respective vertical coloumns. Give special emphasis on the following points :
(i) Electronic configurations
(ii) Oxidation states
(iii) Ionisation enthalpies and
(iv) Atomic sizes.
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Give examples and suggest reasons for the following features of the transition metal chemistry :
(i) The lowest oxide of transition metal is basic, the highest is amphoteric/acidic.
(ii) A transition metal exhibits highest oxidation state in oxides and fluorides.
(iii) The highest oxidation state is exhibited in oxoanions of a metal.
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