Question
What are the similarities between lanthanoids and actinoids?
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| | Column I | | Column II |
| (i) | Catalyst alters the rate of reaction. | (a) | Cannot be fraction or zero. |
| (ii) | Molecularity | (b) | Proper orientation is not there always. |
| (iii) | Second half life of first order reaction | (c) | By lowering the activation energy. |
| (iv) | $\text{e}^{\frac{-\text{Ea}}{\text{RT}}}$ | (d) | Is same as the first. |
| (v) | Energetically favourable reactions are sometimes slow. | (e) | Total probability is one. |
| (vi) | Area under the Maxwell Boltzman curve is constant. | (f) | Refers to the fraction of molecules with energy equal to or greater than activation energy. |
MnO-4+8H++5e-$→$
| Experiment | $[ A ] / mol L ^{-1}$ | $[ B ] / mol L ^{-1}$ | Initial rate $/ mol$ $L ^{-1} min^{-1}$ |
| I | 0.1 | 0.1 | $2.0 \times 10^{-2}$ |
| II | - | 0.2 | $4.0 \times 10^{-2}$ |
| III | 0.4 | 0.4 | - |
| IV | - | 0.2 | $2.0 \times 10^{-2}$ |