Why does compound (A) given below not form an oxime?
Answer
Glucose pentaacetate (structure A) doesn’t have a free —OH group at C1 and so can’t be converted to the open chain form to give —CHO group and hence doesn’t form the oxime.
Amino acids can be classified as $\alpha-, \beta-, \delta-,$and so on depending upon the relative position of amino group with respect to carboxyl group. Which type of amino acids form polypetide chain in proteins?
Answer
$\alpha-$Amino acid,forms polypeptide chain in proteins.
Which moieties of nucleosides are involved in the formation of phosphodiester linkages present in dinucleotides? What does the word diester in the name of linkage indicate? Which acid is involved in the formation of this linkage?
Answer
Nucleosides are linked to phosphoric acid at 5′-position of sugar moiety to form a nucleotide. Further, nucleotides (two molecules) are joined together by phosphodiester linkage between 5′ and 3′ carbon atoms of pentose sugar to form dinucleotide. Phosphoric acid is involved in the formation of this linkage.
In nucleoside a base is attached at 1′ position of sugar moiety. Nucleotide is formed by linking of phosphoric acid unit to the sugar unit of nucleoside. At which position of sugar unit is the phosphoric acid linked in a nucleoside to give a nucleotide?
Answer
Phosphoric acid unit is linked preferably at 5′-position of sugar moiety of a nucleoside to give a nucleotide.
$\alpha-$Helix is a secondary structure of proteins formed by twisting of polypeptide chain into right handed screw like structures. Which type of interactions are responsible for making the $\alpha-$helix structure stable?
Answer
In $\alpha-$helix, apolypeptide chain is stabilized by the formation of hydrogen bonds between NH— group of amino acids in one turn with the >C —O groups of amino acids belonging to adjacent turn.
Activation energy for the acid catalysed hydrolysis of sucrose is $6.22kJ\ mol^{–1},$ while the activation energy is only $2.15kJ\ mol^{–1}$ when hydrolysis is catalysed by the enzyme sucrase. Explain.
Answer
Enzymes are biocatalysts. They reduce the magnitude of activation energy by providing alternative path. In the hydrolysis of sucrose, the enzyme sucrase reduces the activation energy from $6.22kJ\ mol^{-1}$ to $2.15kJ\ mol^{-1}$. As a result, enzyme catalysed reactions occur at a much faster rate than the ordinary chemical reactions using conventional catalysts.
What are glycosidic linkages? In which type of biomolecules are they present?
Answer
The two monosaccharides are joined together by an oxide linkage formed by the loss of a water molecule. Such a linkage between two monosaccharides is held together by a glycosidic linkage between $C_1$ of and $C_2$. Since the reducing groups of glucose and fructose are involved in glycosidic bond formation, between two monosaccharide units through oxygen atom is called glycosidic linkage.
Vitamin C are soluble in water. Water soluble vitamins must be supplied regularly in diet because they are readily excreted in urine and cannot be stored in our body.
What is the structural feature characterising reducing sugars?
Answer
The main structural feature of reducing sugars is the presence of an aldehyde group (-CHO) such as in glucose, mannose, galactose, etc. or a-ketol group (-CO- CH2OH) as present in fructose.