Questions · Page 2 of 2

1 Marks Question

Question 511 Mark
Why is ferric chloride preferred over potassium chloride in case of a cut leading to bleeding?
Answer
$\mathrm{Fe}^{3+}$ ion has greater coagulating power than $\mathrm{K}^{+}$ion as ferric ion has higher charge.
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Question 521 Mark
Why is a colloidal sol stable?
Answer
All the particles in a colloidal sol carry the same charge and hence keep on repelling each other and cannot aggregate together to form bigger particles.
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Question 531 Mark
Why does physisorption decrease with the increase of temperature?
Answer
Physisorption is an exothermic process:
$\text{Solid}+\text{Gas}\rightleftharpoons\text{Gas}/\text{Solid}+\text{Heat}\$\text{Adsorbent})\ \ (\text{Adsorbate})\ \ (\text{gas adsorbed on solid})$
According to Le-Chatelier’s principle, if T is increased, equilibrium shifts in the backward direction i.e., gas is released from the surface of solid.
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Question 541 Mark
Why do colloidal solutions exhibit Tyndall effect?
Answer
Colloidal solutions exhibit Tyndall effect because the size of the colloidal particles (1nm–1000nm) is such that they can scatter light.
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Question 551 Mark
What is meant by chemical adsorption?
Answer
If the adsorbate is held on the surface of the adsorbent as a result of chemical reaction forming surface compounds, it is called chemical adsorption.
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Question 561 Mark
Give the expression of Freundlich isotherms.
Answer
$\frac{\text{x}}{\text{m}}=\text{kp}^\frac{1}{\text{n}}\ \ \ \ \ \ \text{or}\ \ \ \ \ \ \text{log}\frac{\text{x}}{\text{m}}=\text{log k}+\frac{1}{\text{n}}\text{log p}$
where m is the mass of the adsorbent and x is the mass of adsorbate, p is the pressure of the gas and n is an integer.
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Question 571 Mark
How will you distinguish between dispersed phase and dispersion medium in an emulsion?
Answer
Emulsions can be diluted to any extent on adding dispersion medium. The dispersed phase forms a separate layer if added in excess.
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Question 591 Mark
Give reasons for the following:
Smoke passed through charged plates before allowing it to come out of chimneys in factories.
Answer
Smoke is passed through charged plates so that unburnt charged carbon particles get settled between the charged plate leaving behind air free from pollutants.
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Question 601 Mark
Which will be adsorbed more readily on the surface of charcoal and why $\mathrm{NH}_3$ or $\mathrm{CO}_2$ ?
Answer
$\mathrm{NH}_3$ has higher critical temperature than $\mathrm{CO}_2$, i.e., $\mathrm{NH}_3$ is more liquefiable than $\mathrm{CO}_2$. Hence, $\mathrm{NH}_3$ has greater intermolecular forces of attraction and hence will be adsorbed more readily.
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Question 611 Mark
What is Kraft temperature?
Answer
Kraft temperature is the minimum temperature above which the formation of micelles takes place.
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Question 621 Mark
What is electrodialysis?
Answer
It is a process by which colloidal solutions containing ionic impurities are purified. The colloidal solution containing ionic impurities is placed in a bag of parchment paper in distilled water in electric field. The ions come out through parchment paper and the sol is purified.
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Question 641 Mark
What is common in aquasols and solid aerosols? How do they differ?
Answer
Aquasol and solid aerosol both have solid as the dispersed phase. They differ in dispersion medium. Aquasols have water as the dispersion medium while aerosols have gas as the dispersion medium.
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Question 651 Mark
Why is it necessary to remove CO when ammonia is obtained by Haber’s process?
Answer
It is important to remove CO in the synthesis of ammonia as CO adversely affects the activity of the iron catalyst, used in Haber’s process.
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Question 661 Mark
How is adsorption of a gas related to its critical temperature?
Answer
Higher is the critical temperature of a gas, greater is the ease of liquefication, i.e., greater are the van der Waal's forces of attraction and hence greater is the adsorption.
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Question 671 Mark
Define ultrafiltration.
Answer
In this process, colloidal solutions are purified by carrying out filtration through special types of graded filters called ultra-filters. Filter paper allows the passage of electrolyte but does not allow the passage of colloidal particles.
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Question 681 Mark
Explain the terms with suitable examples:
Hydrosol
Answer
A colloidal solution having water as the dispersion medium and a solid as the dispersed phase is called a hydrosol.
For example: starch sol or gold sol.
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Question 691 Mark
Explain the terms with suitable examples:
Aerosol
Answer
A colloidal solution having a gas as the dispersion medium and a solid as the dispersed phase is called an aerosol.
For example: fog.
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Question 701 Mark
Give one example of positively charged sol and one example of negatively charged sol.
Answer
$\mathrm{Fe}(\mathrm{OH})_3$ is a positively charged sol whereas $\mathrm{As}_2 \mathrm{~S}_3$ is a negatively charged colloid.
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Question 721 Mark
What is sorption?
Answer
Sorption is the process in which adsorption and absorption take place simultaneously, e.g., dyeing of cotton fibres by azo dyes.
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Question 731 Mark
What is the main cause of charge on a colloidal solution?
Answer
The charge on the colloidal particles is due to adsorption of common ions of the electrolyte on the surface of the colloidal particles, e.g., $\mathrm{Fe}^3+$ from $\mathrm{FeCl}_3$ on the surface of $\mathrm{Fe}(\mathrm{OH})_3$ particles.
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Question 741 Mark
$\mathrm{Fe}(\mathrm{OH})_3$ colloid positively charged, when prepared by adding $\mathrm{FeCl}_3$ to hot water?
Answer
The adsorption of positively charged $\mathrm{Fe}^{3+}$ ions by the sol of hydrated ferric oxide results in positively charged colloid.
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Question 751 Mark
Give reasons for the following:
Rough surface of catalyst is more effective than smooth surface.
Answer
Rough surface of a catalyst provides more surface area for adsorption.
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Question 761 Mark
Why does the white precipitate of silver halide become coloured in the presence of dye eosin.
Answer
White precipitate of silver chloride becomes coloured due to adsorption of pigments of eosin dye.
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Question 771 Mark
Explain the following terms:
Electrophoresis
Answer
The movement of colloidal particles under the influence of an applied electric field is known as electrophoresis. Positively charged particles move to the cathode, while negatively charged particles move towards the anode. As the particles reach oppositely charged electrodes, they become neutral and get coagulated.
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Question 781 Mark
Explain what is observed
An electrolyte, NaCl is added to hydrated ferric oxide sol.
Answer
When NaCl is added to ferric oxide sol, it dissociates to give $\mathrm{Na}^{+}$and $\mathrm{Cl}^{-}$ions. Particles of ferric oxide sol are positively charged. Thus, they get coagulated in the presence of negatively charged $\mathrm{Cl}^{-}$ions.
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Question 791 Mark
What causes electrophoresis?
Answer
Electrophoresis is due to charge on colloidal particles, the charged particles move towards one of the electrodes in electric field.
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Question 811 Mark
How are colloids classified on the basis of
Interaction between dispersed phase and dispersion medium?
Answer
Colloids can be classified on various bases:
On the basis of the nature of the interaction between the dispersed phase and dispersion medium, the colloids can be classified as lyophilic (solvent attracting) and lyophobic (solvent repelling).
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Question 821 Mark
Give reason why a finely divided substance is more effective as an adsorbent.
Answer
Adsorption is surface phenomenon therefore adsorption is directly proportional to the surface area.
Finely divided substance has greater surface area. Greater is the surface area of the adsorbent, greater would be its absorbent power. That is why a finely divided surface is more effective as an absorbent.
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Question 831 Mark
What is shape selective catalysis?
Answer
A catalytic reaction which depends upon the pore structure of the catalyst and on the size of the reactant and the product molecules is called shape-selective catalysis. For example, catalysis by zeolites is a shape-selective catalysis. The pore size present in the zeolites ranges from 260-740pm. Thus, molecules having a pore size more than this cannot enter the zeolite and undergo the reaction.
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Question 841 Mark
Gelatin which is a peptide is added in icecreams. What can be its role?
Answer
Ice-cream is an emulsion. Gelatin is emulsifying agent which is used to stabilize the emulsion so it is added to ice-creams.
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Question 851 Mark
Explain the following terms:
Coagulation
Answer
The process of settling down of colloidal particles i.e., conversion of a colloid into a precipitate is called coagulation.
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Question 861 Mark
Comment on the statement that “colloid is not a substance but a state of substance”.
Answer
Common salt (a typical crystalloid in an aqueous medium) behaves as a colloid in a benzene medium. Hence, we can say that a colloidal substance does not represent a separate class of substances. When the size of the solute particle lies between 1 nm and 1000 nm, it behaves as a colloid.
Hence, we can say that colloid is not a substance but a state of the substance which is dependent on the size of the particle. A colloidal state is intermediate between a true solution and a suspension.
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Question 871 Mark
Why are powdered substances more effective adsorbents than their crystalline forms?
Answer
Powderded substance are more effective adsorbent than their crystalline forms because when a substance is powdered its surface area increase and physisorption is directly proportional to the surface area of adsorbent
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Question 881 Mark
What happens when gelatin is mixed with gold sol?
Answer
Gelatin stabilises the colloidal solution of gold. Gold sol is lyophobic sol or solvent repelling sol.
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1 Marks Question - Page 2 - Chemistry STD 12 Science Questions - Vidyadip