Questions

SECTION - A [CHEMISTY - MCQ]

Take a timed test

45 questions · 39 auto-graded MCQ + 6 self-marked written.

MCQ 14 Marks
When HCI react's with finely powdered iron, which of the following is produced?
  • $FeCl _2+ H _2$
  • B
    $FeCl _3+ H _2$
  • C
    Both 1 and 2
  • D
    Only $FeCl _2$
Answer
Correct option: A.
$FeCl _2+ H _2$
A
View full question & answer
MCQ 24 Marks
Correct order of catenation tendency:
  • A
    $C > Si > Ge > Sn$
  • $C \gg Si > Ge \simeq Sn$
  • C
    $Si > C > Sn > Ge$
  • D
    $Ge > Sn > Si > C$
Answer
Correct option: B.
$C \gg Si > Ge \simeq Sn$
(B) $C \gg Si > Ge \simeq Sn$,
Correct order of catenation tendency
View full question & answer
MCQ 34 Marks
Which of the following does not exist?
  • A
    $XeOF _4$
  • $NeF _2$
  • C
    $XeF _2$
  • D
    $XeF _6$
Answer
Correct option: B.
$NeF _2$
B
View full question & answer
MCQ 44 Marks
Correct order of C-O bond length among CO, $CO _3^{-2}, CO _2$ is
  • A
    $CO < CO _3^{-2}< CO _2$
  • B
    $CO _3^{-2}< CO _2< CO$
  • $CO < CO _2< CO _3^{-2}$
  • D
    $CO _2< CO < CO _3^{-2}$
Answer
Correct option: C.
$CO < CO _2< CO _3^{-2}$
C
View full question & answer
MCQ 74 Marks
Cyclohexylamine when treated with nitrous acid yields (P). On treating (P) with PCC results in (Q). When (Q) is heated with dil. NaOH we get ( R ). The final product ( $R$ ) is :
  • A

    Image
  • B

    Image
  • C

    Image
  • D

    Image
Answer
View full question & answer
MCQ 104 Marks
The structure of major products A, B and C in the following reaction sequence are:
Image
  • A

    Image
  • B

    Image
  • C

    Image

  • Image
Answer
Correct option: D.

Image
D
View full question & answer
MCQ 164 Marks
Match list-l with list-ll
List - lList - lI
(A) $\left[ Ni ( Cl )_4\right]^{-2}$(i) 5.92 Β.Μ.
(B) $\left[ Co \left( C _2 O _4\right)_3\right]^{-3}$(ii) 1.73 B.M
(C) $\left[ FeF _6\right]^{-3}$(iii) 0 B.M.
(D) $\left[ Mn ( CN )_6\right]^{-}$(iv) 2.82 Β.Μ.
Choose the correct answer from the options given below:
  • (A)-(iv), (B)-(iii), (C)-(i), (D)-(ii)
  • B
    A-(iv), (B)-(iii), (C)- (ii), (D)-(i)
  • C
    (A)-(iii), (B)-(iv), (C)-(i), (D)-(ii)
  • D
    (A)-(i), (B)-(iii), (C)-(ii), (D)-(iv)
Answer
Correct option: A.
(A)-(iv), (B)-(iii), (C)-(i), (D)-(ii)
A
View full question & answer
MCQ 174 Marks
Maximum number of isomeric monochloro derivatives which can be obtained from 2,2,5,5-tetramethylhexane by chlorination is (excluding stereo isomer)
  • A
    3
  • 2
  • C
    4
  • D
    5
Answer
Correct option: B.
2
B
View full question & answer
MCQ 184 Marks
When 0.01 mol of an organic compound containing $60 \%$ carbon was burnt completely, 4.4 g of $CO _2$ was produced. The molar mass of compound in g $mol ^{-1}$ is
  • A
    150
  • B
    250
  • C
    100
  • 200
Answer
Correct option: D.
200
D
View full question & answer
MCQ 194 Marks
In which of the compound does hydrogen have an oxidation state of $- 1$ ?
  • A
    $CH _4$
  • B
    $NH _3$
  • C
    HCl
  • $CaH _2$
Answer
Correct option: D.
$CaH _2$
D
View full question & answer
MCQ 204 Marks
The equilibrium constant for the reaction $Zn ( s )+ Sn ^{2+}( aq ) \rightleftharpoons Zn ^{2+}( aq )+ Sn ( s )$ is $1 \times 10^{20}$ at 298 K. The magnitude of standard electrode potential of $Sn / Sn ^{2+}$ if $E _{ Zn ^{2+} / Zn }^{\circ}=-0.76 V$
Given : $\frac{2.303 R T}{F}=0.059 V$
  • A
    $12 \times 10^{-2} V$
  • $17 \times 10^{-2} V$
  • C
    $28 \times 10^{-2} V$
  • D
    $22 \times 10^{-2} V$
Answer
Correct option: B.
$17 \times 10^{-2} V$
B
View full question & answer
MCQ 214 Marks
The standard electrode potential $\left( M ^{3+} / M ^{2+}\right)$ for V , Cr Mn & Co are $-0.26 V,-0.41 V,+1.57 V$ and $+1.97 V$ , respectively. The metal ions which can liberate $H _2$ from a dilute acid are
  • A
    $V ^{2+}$ and $Mn ^{2+}$
  • B
    $Cr ^{2+}$ and $Co ^{2+}$
  • $V ^{2+}$ and $Cr ^{2+}$
  • D
    $Mn ^{2+}$ and $Co ^{2+}$
Answer
Correct option: C.
$V ^{2+}$ and $Cr ^{2+}$
(C) $V ^{2+}$ and $Cr ^{2+}$,
A.S. $\propto \frac{- M ,- I }{+ M ,+1}$
View full question & answer
MCQ 224 Marks
How much amount of KCl is added in 500g of water to decrease the freezing point of water to $-0.2^{\circ} C$
$\left[K_{f}\left(H_2 O\right)=2 K Kg mol^{-1}\right]$
  • A
    3.725 g
  • B
    7.4 g
  • 1.8625 g
  • D
    6.2 g
Answer
Correct option: C.
1.8625 g
(C) 1.8625 g,
$\Delta T _{ f }= i . K _{ f } \cdot m$
View full question & answer
MCQ 234 Marks
Image
The major product obtained would be:
  • A

    Image
  • B

    Image

  • Image
  • D

    Image
Answer
Correct option: C.

Image
(C)
Image,
Image
Electrophilic addition reaction of alkene
View full question & answer
MCQ 284 Marks
Which among the following species does not exist in normal condition?
  • A
    $He _2^{+}$
  • B
    $H _2^{+}$
  • C
    $H _2^{-}$
  • $Be _2$
Answer
Correct option: D.
$Be _2$
D
View full question & answer
MCQ 294 Marks
Which has highest pKa value among phenol is
  • A
    2,4-Dinitrophenol
  • B
    4-Nitrophenol
  • 2, 4, 5-Trimethylphenol
  • D
    3-Chlorophenol
Answer
Correct option: C.
2, 4, 5-Trimethylphenol
(C) 2, 4, 5-Trimethylphenol,
Highest pKa value among phenol is 2, 4, 5-Trimethylphenol
View full question & answer
MCQ 304 Marks
In the depression of freezing point experiment
A. Vapour pressure of the solution is less than that of pure solvent
B. Vapour pressure of the solution is more than that of pure solvent
C. Only solute molecules solidify at the freezing point
D. Only solvent molecules solidify at the freezing point 
which statement(s) is/are correct.
  • A and D only
  • B
    B and C only
  • C
    A and C only
  • D
    A only
Answer
Correct option: A.
A and D only
(A) A and D only,
A. Vapour pressure of the solution is less than that of pure solvent
D. Only solvent molecules solidify at the freezing point
View full question & answer
MCQ 314 Marks
In which of the following molecule/ions $BF _3, NO _2^{-}$, $NH _2^{-}$and $H _2 O$, the central atom is $s p ^{ 2 }$ hybridized
  • $BF 3$ and $NO _2^{-}$
  • B
    $NO _2^{-}$and $NH _2^{-}$
  • C
    $NH _2^{-}$and $H _2 O$
  • D
    $NO _2^{-}$and $H _2 O$
Answer
Correct option: A.
$BF 3$ and $NO _2^{-}$
A
View full question & answer
MCQ 324 Marks
If $\Delta_0< P$ then correct configuration for $d^4$ would be-
  • $t _{2 g}{ }^3 eg ^1$
  • B
    $t _{2 g}{ }^4 eg ^0$
  • C
    $t _{2 g}{ }^2 eg ^2$
  • D
    $t_{2 g}{ }^0 eg ^4$
Answer
Correct option: A.
$t _{2 g}{ }^3 eg ^1$
A
View full question & answer
MCQ 334 Marks
Select equations having exothermic step:
  • A
    $S ^{-}( g )+ e ^{-}( g ) \rightarrow S ^{2-}( g )$
  • B
    $Ne ( g )+ e ^{-}( g ) \rightarrow Ne ^{-}( g )$
  • C
    $N ( g )+ e ^{-}( g ) \rightarrow N ^{-}( g )$
  • $P ( g )+ e ^{-}( g ) \rightarrow P ^{-}( g )$
Answer
Correct option: D.
$P ( g )+ e ^{-}( g ) \rightarrow P ^{-}( g )$
(D) $P ( g )+ e ^{-}( g ) \rightarrow P ^{-}( g )$,
Exothermic step $P ( g )+ e ^{-}( g ) \rightarrow P ^{-}( g )$
View full question & answer
MCQ 344 Marks
Consider the variation of ionization energy across the $3^{\text {rd }}$ period $L \rightarrow R$. (Left to right) What is the element E?
Image
  • A
    Na
  • B
    S
  • P
  • D
    Cl
Answer
Correct option: C.
P
C
View full question & answer
MCQ 354 Marks
If atomic radius of Fluorine is X and for Neon is Y, then what is relation between $X$ and $Y$ ?
  • A
    $X>Y$
  • $X< Y$
  • C
    $X=Y$
  • D
    None
Answer
Correct option: B.
$X< Y$
B
View full question & answer
MCQ 364 Marks
How many elements present in $4^{\text {th }}$ period which are having electrons of 4d subshell?
  • A
    10
  • B
    8
  • $0$
  • D
    2
Answer
Correct option: C.
$0$
C
View full question & answer
MCQ 374 Marks
The total spin of ${ }_{25} Fe ^{ x +}$ is $\pm \frac{5}{2}$. The value of x is:
  • A
    1
  • B
    2
  • 3
  • D
    4
Answer
Correct option: C.
3
(C) 3
The value of $x$ is 3
View full question & answer
MCQ 394 Marks
The dissociation constant of acetic acid is $x \times 10^{-5}$. When 25 mL of $0.2\ M\ CH _3 COONa$ solution is mixed with 25 mL of $0.02\ M\ CH _3 COOH$ solution, the pH of the resultant solution is found to be equal to 5. The value of $x$ is
  • 10
  • B
    8
  • C
    6
  • D
    2
Answer
Correct option: A.
10
(A) 10
$K_a=c \alpha^2$
View full question & answer
MCQ 404 Marks
For the reversible reaction
$N _2 O _4(g) \rightleftharpoons 2 NO _2(g)$-heat
The equilibrium will be disturbed -
  • A
    By decreasing concentration of $NO _2(g)$
  • B
    By increasing pressure and decreasing temperature
  • C
    By adding $Ne ( g )$ at constant volume
  • Both (1) and (2)
Answer
Correct option: D.
Both (1) and (2)
(D) Both (1) and (2),
(1) By decreasing concentration of $NO _2(g)$
(2) By increasing pressure and decreasing temperature
View full question & answer
MCQ 414 Marks
The heat of reaction for
$MO \rightarrow M +\frac{1}{2} O _2$ is 50 kcal and
$MO _2 \rightarrow MO +\frac{1}{2} O _2$ is -100 kcal.
The heat of reaction for $M + O _2 \rightarrow MO _2$ is -
  • A
    -50 kcal
  • B
    -150 kcal
  • 50 kcal
  • D
    +150 kcal
Answer
Correct option: C.
50 kcal
C
View full question & answer
MCQ 424 Marks
Assertion (A): Internal energy of an ideal gas at a particular temperature does not depend on volume.
Reason (R): State function depends only on temperature.
  • A
    Both Assertion and Reason are true and Reason is correct explanation of the Assertion.
  • B
    Both Assertion and Reason are true but Reason is not a correct explanation of the Assertion.
  • Assertion is true but Reason is false.
  • D
    Both Assertion and Reason are false.
Answer
Correct option: C.
Assertion is true but Reason is false.
C
View full question & answer
MCQ 434 Marks
If color of $\left[ Ni \left( H _2 O \right)_6\right]_{( aq )}^{+2}$ is green then what would be the color of $\left[ Ni ( en )_3\right]_{( aq )}^{ +2 }$ ?
  • Violet
  • B
    Red
  • C
    Orange
  • D
    Can't predict
Answer
Correct option: A.
Violet
A
View full question & answer
MCQ 444 Marks
Assume that the radius of the first Bohr orbit of hydrogen atom is $0.6 Å$. The radius of the third Bohr orbit of $He ^{+}$in picometer is -
  • A
    240
  • B
    300
  • 270
  • D
    320
Answer
Correct option: C.
270
C
View full question & answer
MCQ 454 Marks
250 mL of 0.1 M solution of $C _2 O _4{ }^{-2}$ in acidic medium completely reduce
  • A
    200 mL of $0.1 M KMnO _4$ solution
  • B
    250 mL of $0.2 M K _2 Cr _2 O _7$ solution
  • 100 mL of $0.1 M KMnO _4$ solution
  • D
    100 mL of $0.1 M K _2 Cr _2 O _7$ solu
Answer
Correct option: C.
100 mL of $0.1 M KMnO _4$ solution
C
View full question & answer