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Question 13 Marks
State one relevant observation for each of the following reactions :
(i) Ammonium hydroxide solution is added to zinc nitrate solution in minimum quantities and then in excess.
(ii) Action of Sodium hydroxide solution on ferrous sulphate solution.
(iii) Lead nitrate solution is treated with sodium hydroxide solution drop wise till it is in excess.
Answer
(i) A white gelatin like precipitate is formed which dissolves in excess of ammonium hydroxide.
(ii) A dirty green precipitate is formed which is insoluble in excess of sodium hydroxide solution.
(iii) A chalky white precipitate of lead (II) hydroxide is formed. But when excess of sodium hydroxide is added then such precipitate dissolves to from a clear solution.
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Question 23 Marks
State one relevant observation for each of the following reactions :
(i) Excess of ammonium hydroxide solution is added to lead nitrate solution.
(ii) Sodium hydroxide solution is added to ferric chloride solution at first a little and then in excess.
(iii) Ammonium hydroxide solution is added to copper (II) nitrate solution in small quantities and then in excess.
Answer
(i) It forms a chalky white precipitate which does not dissolve in excess of ammonium hydroxide.
(ii) A reddish brown precipitate is formed, which does not dissolve in excess of sodium hydroxide solution.
(iii) With small amount of ammonium hydroxide, a bluish white precipitate is formed. This precipitate dissolves in excess of ammonium hydroxide to form a deep blue solution.
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Question 33 Marks
(a) Distinguish between Qualitative and Quantitative analysis.
(b) Define Reagent
(c) Define Precipitate
Answer
(a) Qualitative Analysis: Process of identification of an unknown substance using a known substance. Quantitative Analysis: Process of determination of chemical composition of a substance.
(b) Reagent: Substance that reacts with another substance.
(c) Precipitate: When solutions are mixed, there is a formation of an insoluble substance.
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Question 43 Marks
In a chemistry lab, a student is given a solution containing an unknown cation. The student adds sodium hydroxide (NaOH) to the solution and observes the formation of a blue precipitate. The student then decides to add ammonium hydroxide to a fresh sample of the solution in excess.
(a) Identify the cation.
(b) What happens when excess of NaOH is added in the solution?
(c) What happens when excess of ammonium hydroxide is added to the solution?
Answer
(a) The cation must be Cu2+.
(b) Deep blue ppt. is insoluble in excess of NaOH.
(c) Pale blue ppt. is soluble in excess of NH4OH.
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Question 53 Marks
A student performs an experiment to identify an unknown cation present in a solution. The student adds a few drops of sodium hydroxide (NaOH) to the solution and observes the formation of a chalky white precipitate. When an excess of NaOH is added, the precipitate dissolves, forming a clear solution.
(a) Identify the cation.
(b) Write the balanced chemical equation for the reaction that leads to the formation of the white precipitate.
(c) What happens to the white precipitate when an excess of NH4OH is added?
Answer
(a) The cation must be Pb2+.
(b) $Pb \left( NO _3\right)_2+2 NaOH \longrightarrow Pb ( OH )_2 \downarrow+2 NaNO _3$
(c) White precipitate is insoluble in excess of NH4OH.
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[3 Mark Question Answer] - Chemistry STD 10 Questions - Vidyadip