Question
A student performs an experiment to identify an unknown cation present in a solution. The student adds a few drops of sodium hydroxide (NaOH) to the solution and observes the formation of a chalky white precipitate. When an excess of NaOH is added, the precipitate dissolves, forming a clear solution.
(a) Identify the cation.
(b) Write the balanced chemical equation for the reaction that leads to the formation of the white precipitate.
(c) What happens to the white precipitate when an excess of NH4OH is added?

Answer

(a) The cation must be Pb2+.
(b) $Pb \left( NO _3\right)_2+2 NaOH \longrightarrow Pb ( OH )_2 \downarrow+2 NaNO _3$
(c) White precipitate is insoluble in excess of NH4OH.

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