Question 13 Marks
Specific heat of Argon at constant Pressure is $0.125 cal / g / K$ and at constant volume is $0.075 cal / g / K$. Calculate the density of Argon at N.T.P. Given that $J =4.2$ Joule/cal?
Answer
View full question & answer→Specific heat of argon at constant pressure, $C _{ P }=0.125 cal / g / K$
$
\begin{aligned}
& \left.C_{P}=0.125 \times 4.2 \times 1000 J / Kg / K \text { (using } 1 cal=4.2 J\right) \\
& C_{P}=525 J / Kg / K \ldots(i)
\end{aligned}
$
Specific heat of argon at constant volume, $C _{ V }=0.075 cal / g / K$
$
C_V=0.075 \times 4.2 \times 1000=315 J / Kg / K
$
The gas constant, r for 1 kg of gas is given by:-
$
r=C_P-C_V=525-315=210 J / Kg / K
$
$
\begin{aligned}
& \text { Normal pressure }=P=h P g=0.76 \times 13600 \times 9.8=101292.8 N / m^2 \\
& \text { Normal Temperature }=T=273 K .
\end{aligned}
$
$
\begin{aligned}
& \text { Suppose } V=\text { Volume of argon gas at } N \text {. T. P. } \\
& PV=nrT \\
& \text { for } n=1 mole \\
& \frac{P V}{T}=r
\end{aligned}
$
$
\begin{aligned}
& V=\frac{r T}{P}=\frac{210 \times 273}{101292.8}=0.566 m^3 \\
& \rho=\frac{\text { Mass }}{\text { Volume }}=\frac{1}{0.566}=1.8 Kg / m^3
\end{aligned}
$
Hence the density of argon is $1.8 Kg / m ^3$.
$
\begin{aligned}
& \left.C_{P}=0.125 \times 4.2 \times 1000 J / Kg / K \text { (using } 1 cal=4.2 J\right) \\
& C_{P}=525 J / Kg / K \ldots(i)
\end{aligned}
$
Specific heat of argon at constant volume, $C _{ V }=0.075 cal / g / K$
$
C_V=0.075 \times 4.2 \times 1000=315 J / Kg / K
$
The gas constant, r for 1 kg of gas is given by:-
$
r=C_P-C_V=525-315=210 J / Kg / K
$
$
\begin{aligned}
& \text { Normal pressure }=P=h P g=0.76 \times 13600 \times 9.8=101292.8 N / m^2 \\
& \text { Normal Temperature }=T=273 K .
\end{aligned}
$
$
\begin{aligned}
& \text { Suppose } V=\text { Volume of argon gas at } N \text {. T. P. } \\
& PV=nrT \\
& \text { for } n=1 mole \\
& \frac{P V}{T}=r
\end{aligned}
$
$
\begin{aligned}
& V=\frac{r T}{P}=\frac{210 \times 273}{101292.8}=0.566 m^3 \\
& \rho=\frac{\text { Mass }}{\text { Volume }}=\frac{1}{0.566}=1.8 Kg / m^3
\end{aligned}
$
Hence the density of argon is $1.8 Kg / m ^3$.



