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Question 15 Marks
Consider one mole of perfect gas in a cylinder of unit cross section with a piston attached (Fig.) A spring (spring constant k) is attached (unstretched length L) to the piston and to the bottom of the cylinder. Initially the spring is unstretched and the gas is in equilibrium. A certain amount of heat Q is supplied to the gas causing an increase of volume from Vo to V1.

  1. What is the initial pressure of the system.
  2. What is the final pressure of the system.
  3. Uing the first law of thermodynamics, write down a relation between Q, Pa, V, Vo and k.
Answer
  1. It is considered that piston is mass less and piston is balanced by atmospheric pressure (Pa). So the initial pressure of system inside the cylinder = Pa,
  2. On supply heat Q. Volume of gas increase from V0 to Vand spring stretched also.So increase in volume = V1 - V0

If displacement of piston is x then volume increase in cylinder ) 

= Aera of base × height = A × x

A × x = V1 - V0 (A = area of cross section of cylinder)

$\therefore\ \text{x}=\frac{\text{V}_1-\text{V}_0}{\text{A}}$

Force exerted by spring $\text{F}_\text{s}=\text{K}_\text{x}=\frac{\text{K}(\text{V}_1-\text{V}_0)}{\text{A}}$

As the piston is of unit area of cross - section $\therefore\ \text{A}=1$

Force due to spring =$\text{K}(\text{V}_1-\text{V}_0)$ on unit area can be say press due to spring = $\text{K}(\text{V}_1-\text{V}_0)$

Final total pressure on gas $\text{P}_\text{f}=\text{P}_\text{a}+\text{K}(\text{V}_1-\text{V}_0)$

  1. by 1st law of thermodynamics $\text{dQ}=\text{dU}+\text{dW}$

Now $\text{DQ}=\text{dU}+\text{dW}$

$=\text{c}_\text{v}(\text{T}-\text{T}_0)+\text{P}_\text{a}(\text{V}_1-\text{V}_0)+\frac{1}{2}\text{kx}^2$

$\text{dQ}=\text{C}_\text{V}(\text{T}-\text{T}_0)+\text{P}_\text{a}(\text{V}_1-\text{V}_0)+\frac{1}{2}\text{k}(\text{V}_1-\text{V}_0)^2$

It is required relation.

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Question 25 Marks
A cycle followed by an engine (made of one mole of perfect gas in a cylinder with a piston) is shown in Fig.

A to B : volume constant

B to C : adiabatic

C to D : volume constant

D to A : adiabatic

V= V= 2V= 2VB

  1. In which part of the cycle heat is supplied to the engine from outside?
  2. In which part of the cycle heat is being given to the surrounding by the engine?
  3. What is the work done by the engine in one cycle? Write your answer in term of PA, PB, VA.
  4. What is the efficiency of the engine?[$\gamma=\frac{5}{3}$ for the gas], $\big(\text{C}_\text{v}=\frac{3}{2}\text{R for one mole}\big)$
Answer

(a) A to B

(b) C to D

(c) $\text{W}_\text{AB}=\int\limits^\text{B}_\text{A}\text{pdV}=0;\text{W}_\text{CD}=0.$

Simillarly. $\text{W}_\text{BC}=\Big[\int\limits^\text{C}_\text{B}\text{pdV}=\text{k}\int\limits^\text{C}_\text{B}\frac{\text{dV}}{\text{V}^\text{r}}=\text{k}\frac{\text{V}^\text{-r+1}}{-\text{R}+1}\Big]^{\text{V}_{\text{C}}}_{\text{V}_\text{B}}$

$= \frac{1}{1-\gamma}(\text{P}_\text{c}\text{V}_\text{c}-\text{P}_\text{B}\text{V}_\text{B})$

Simillarly, $\text{W}_\text{DA}=\frac{1}{1-\gamma}(\text{P}_\text{A}\text{V}_\text{A}-\text{P}_\text{D}\text{V}_\text{D})$

Now $\text{P}_\text{C}=\text{P}_\text{B}\Big(\frac{\text{V}_\text{B}}{\text{V}_\text{C}}\Big)^\gamma=2^{-\gamma}\text{P}_\text{B}$

Simillarly, $\text{P}_\text{D}=\text{P}_\text{A}2^{-\gamma}$

Total work done $=\text{W}_\text{BC}+\text{W}_\text{DA}$

$=\frac{1}{1-\gamma}\big[\text{P}_\text{B}\text{V}_\text{B}\big(2^{-\gamma+1}-1\big)-\text{P}_\text{A}\text{V}_\text{A}\big(2^{-\gamma+1}-1\big)\big]$

$=\frac{1}{1-\gamma}\big(2^{1-\gamma}-1\big)\big(\text{P}_\text{B}-\text{P}_\text{A}\big)\text{V}_\text{A}$

$=\frac{3}{2}\big(1-\Big(\frac{1}{2}\Big)^\frac{2}{3}\big)\big(\text{P}_\text{B}-\text{P}_\text{A}\big)\text{V}_\text{A}$

  1. Heat supplied during process A, B 

$\text{d}\text{Q}_\text{AB}=\text{d}\text{U}_\text{AB}$

$\text{Q}_\text{AB}=\frac{3}{2}\text{n}\text{R}\big(\text{T}_\text{B}-\text{T}_\text{A}\big)\text{V}_\text{A}$

$\text{Efficiency}=\frac{\text{Net Work done }}{\text{Heat Supplied}}=\Big[1-\Big(\frac{1}{2}\Big)^\frac{2}{3}\Big]$

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Question 35 Marks
A cycle followed by an engine (made of one mole of an ideal gas in a cylinder with a piston) is shown in Fig. Find heat exchanged by the engine, with the surroundings for each section of the cycle. (Cv = (3/2) R)

AB : constant volume

BC : constant pressur

CD : adiabati

DA : constant pressure

Answer
  1. : For A → B, dV = 0 

so,$\text{dW}=\int\text{P}.\text{dV}=\int\text{p}\times0=0$

$\text{dW}=0$

By $1^\text{st}$ law of thermodynamics

$\text{dQ}=\text{dU}+\text{dW}=\text{dU}+0$

$\therefore\ \text{dQ} =\text{dU}$

$\big(\text{dQ}=\text{n}\text{C}_\text{V}\text{dT}\big)$

So, $\text{dQ}-1\frac{3}{2}\text{R}\big(\text{T}_\text{B}-\text{T}_\text{A}\big).....(\text{i})$

$\text{dU}=\text{dQ}=\frac{3}{2}\big(\text{R}\text{T}_\text{}B-\text{R}\text{T}_\text{A}\big)=\frac{3}{2}\big(\text{P}_\text{B}\text{V}_\text{B}-\text{P}_\text{A}\text{}V_\text{A}\big)$

$\therefore$  Heat exchange [to system]

$\text{dQ}_1=\text{dU}=\frac{3}{2}\big(\text{P}_\text{s}\text{V}_\text{s}-\text{P}_\text{A}\text{V}_\text{A}\big)$

  1. For B to C, $\Delta\text{P}=0\ \text{n}=1$

$\text{dQ}=\text{dU}+\text{dW}=\text{C}_\text{V}\text{(dT)}+\text{P}_\text{S}\text{dV}$

$\text{dQ}_2=\frac{3}{2}\text{R}\big(\text{T}_\text{C}-\text{T}_\text{B}\big)+\text{P}_\text{B}\big(\text{V}_\text{C}-\text{V}_\text{B}\big)$

$=\frac{3}{2}\big(\text{T}_\text{C}\text{R}-\text{RT}_\text{B}\big)+\text{P}_\text{B}\text{V}_\text{C}-\text{P}_\text{B}\text{V}_\text{B}$

$=\frac{3}{2}[\text{P}_\text{C}\text{V}_\text{C}]-\frac{3}{2}[\text{P}_\text{B}\text{V}_\text{B}]-\text{P}_\text{B}\text{V}_\text{B}-\text{P}_\text{B}\text{V}_\text{C}$

$\text{V}_\text{A}=\text{V}_\text{B}\ \text{and}\ \text{P}_\text{B}=\text{P}_\text{C}$

$\therefore\text{dQ}_2=\frac{3}{2}\text{P}_\text{B}\text{V}_\text{C}-\frac{3}{2}\text{P}_\text{B}\text{V}_\text{A}-\text{P}_\text{B}\text{V}_\text{A}+\text{P}_\text{B}\text{V}_\text{C}$

$=\frac{5}{2}\text{P}_\text{B}\text{V}_\text{C}-\frac{5}{2}\text{P}_\text{B}\text{V}_\text{A}$

$\text{dQ}_2=\frac{5}{2}\text{P}_\text{B}[\text{V}_\text{C}-\text{V}_\text{A}]$

  1.  For diagram C → B,  adiabatic change

$\text{dQ}_3=0$  (No exchange of heat )

  1.  For diagram D  →  A, $\Delta\text{P}=0$ Compression of gas from volume VD to VA  pressure hence heat exchange similar to part (b) i.e. Heat exchange$\text{dQ}_3=\frac{5}{2}\text{P}_\text{A}\big(\text{V}_\text{A}-\text{V}_\text{D}\big)$
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Question 45 Marks
In a refrigerator one removes heat from a lower temperature and deposits to the surroundings at a higher temperature. In this process, mechanical work has to be done which is provided by an electric motor. If the motor is of 1KW power, and heat is transferred from –3°C to 27°C, find the heat taken out of the refrigerator per second assuming its efficiency is 50% of a perfect engine.
Answer
Carton's engine is perfect heat engine operating between two tempreature T1  and  T(source and sink). Refrigerator is aiso carnot's engine working in reverse order its efficiency in $\eta$

$\eta=1-\frac{\text{T}_{2}}{\text{T}_{2}}=1-\frac{273-3}{273+27}=1-\frac{270}{300}=-.9=1=\frac{1}{10}$

Efficiency of refrigerator's 50 % of perfect engine

$\therefore$ Efficiency of refrigerator = 50% of 1 = 0.5

Net efficiency = $\eta'$ = 0.5 × 0.1 = 0.05

$\therefore$ Cofficient of performence $\beta=\frac{\text{Q}_{2}}{\text{W}}=\frac{1-\eta'}{\eta'}$

$\beta=\frac{1-0.05}{0.05} =\frac{0.95}{0.05}=19$

Q2 = 19% W .D. by motor on refrigerator

= 19 × 1KW =19KJ/ s

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Question 55 Marks
Consider a cycle tyre being filled with air by a pump. Let V be the volume of the tyre (fixed) and at each stroke of the pump $\Delta\text{V}(<<\text{V})$ of air is transferred to the tube adiabatically. What is the work done when the pressure in the tube is increased from P1 to P2?
Answer
Air is transferred into tyre adiabatically let initial volume of air in tyre V and after pumping one stroke it become (V + dV) and pressure increase from P to (P + dP) then 

$\text{P}_{1}\text{V}_{1}^\gamma=\text{P}_{2}\text{V}_{2}^\gamma$

$\text{P}(\text{d}+\text{dv})^\gamma=(\text{P}+\text{dp})\text{V}^\gamma$

$\text{PV}\Big[1+\frac{\text{dV}}{\text{V}}\Big]^\gamma=\text{P}\Big[1+\frac{\text{dP}}{\text{P}}\Big]\text{V}^\gamma$

As volume of tyre V remains constant 

$\text{PV}^\gamma\Big[1+\gamma\frac{\text{dV}}{\text{V}}\Big]=\text{PV}^\gamma\Big[1+\frac{\text{dP}}{\text{P}}\Big]$

$\big[$on expanding by binomial theorm neglecting the higher terms of $\Delta\text{V}$ as $\Delta\text{V}<<\text{V}\big]$

$1+\gamma\frac{\text{dV}}{\text{V}}=1+\frac{\text{dP}}{\text{P}}$

$\text{dV}=\frac{\text{VdP}}{\gamma\text{P}}$

Integrating both side in limits W1 to W2 and P→ P2

$\int\text{pdV}=\int\limits^{\text{p}_2}_{\text{p}_1}\frac{\text{VdP}}{\gamma}$

$\int\limits^{\text{w}_2}_{\text{w}_1}\text{dw}=\frac{\text{V}}{\gamma}(\text{P}_{2}-\text{P}_{1})(\text{V}=\text{constant})$

$\text{W}=\frac{(\text{P}_{2}-\text{P}_{1})\text{V}}{\gamma}$

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Question 65 Marks
Consider that an ideal gas (n moles) is expanding in a process given by P = f( V ), which passes through a point (V0, P0 ). Show that the gas is absorbing heat at (P0, V0 ) if the slope of the curve P = f(V ) is larger than the slope of the adiabat passing through (P0, V0 ).
Answer
slope of graph at  $\big(\text{V}_0,\text{P}_0\big)=\Big(\frac{\text{dP}}{\text{dV}}\Big)_{(\text{V}_0\text{P}_0)}$

$\text{P}=\text{f}(\text{V})$ for adiabatic process $\text{PV}^\gamma$ = constant (K)

 $\text{Or}\ \text{P}=\frac{\text{K}}{\text{V}^\gamma}\ \text{or}\ \frac{\text{dP}}{\text{dV}}=\text{K}\big(-\gamma\big)\text{V}^{-\gamma-1}$

$\frac{\text{dP}}{\text{dV}}=-\gamma\text{PV}^\gamma\text{V}^{-\gamma}\text{V}^{-1}=-\frac{\gamma\text{P}}{\text{V}}$

$\Big(\frac{\text{dP}}{\text{dV}}\Big)_{\text{(P}_0\text{V}_0)}=\frac{-\gamma\text{P}_0}{\text{V}_0}$ Heat absorbed by in the process $$$\text{P}=\text{f}(\text{V})$

$\text{dQ}=\text{dU}+\text{dW}$

$\text{dQ}=\text{n}\text{C}_\text{V}\text{dT}+\text{PdV}\ .....(\text{i})$

$\text{PV}=\text{nRT}$

$\text{T}=\frac{\text{PV}}{\text{nR}}=\frac{\text{V}}{\text{nR}}\text{f}(\text{V})$

$\frac{\text{dT}}{\text{dV}}=\frac{1}{\text{nR}}\big[\text{f}(\text{V})+\text{Vf}\ '(\text{V})\big]$

$\frac{\text{dQ}}{\text{dV}}=\text{nC}_\text{V}\frac{\text{dT}}{\text{dV}}+\text{P}.\frac{\text{dV}}{\text{dV}}=\frac{\text{nC}_\text{V}}{\text{nR}}$$\big[\text{f(V)}+\text{Vf}\ '\text{(V)}\big]+\text{P}$

$\Big(\frac{\text{dQ}}{\text{dV}}\Big)_{\text{V}-\text{V}_0}=\frac{\text{C}_\text{V}}{\text{R}}$$\big[\text{f}(\text{V}_0)+\text{V}_0\text{f}\ '(\text{V}_0)\big]+\text{f}_0\text{V})$$\big[\because\text{P}=\text{f}(\text{V})\text{ given}\big]$

$=\text{f}(\text{V}_0)\Big[\frac{\text{C}_\text{V}}{\text{R}}+1\Big]+\text{V}_0\text{f}\ '(\text{V}_0)\frac{\text{C}_\text{V}}{\text{R}}$

$\text{C}_\text{P}-\text{C}_\text{V}=\text{R}\Rightarrow\frac{\text{C}_\text{P}}{\text{C}_\text{V}}-1=\frac{\text{R}}{\text{C}_\text{V}}$

$\therefore\gamma-1=\frac{\text{R}}{\text{C}_\text{V}}\Rightarrow\text{C}_\text{V}=\frac{\text{R}}{\gamma-1}\Rightarrow\frac{\text{C}_\text{V}}{\text{R}}=\frac{1}{\gamma-1}$

$\Big(\frac{\text{dQ}}{\text{dV}}\Big)_{\text{V-V}_0}=\text{f}(\text{V}_0)\Big[\frac{1}{\gamma-1}\Big]+\text{V}_0\text{f}\ '(\text{V}_0)\frac{1}{\gamma-1}$

$=\text{f}(\text{V}_0)\Big[\frac{1+\gamma-1}{\gamma-1}\Big]+\frac{\text{V}_0\text{f}\ '(\text{V}_0)}{\gamma-1}$

$=\frac{\gamma}{(\gamma-1)}\text{f}(\text{V}_0)+\text{V}_0\frac{\text{f}\ '(\text{V}_0)}{\gamma-1}$

$=\frac{1}{(\gamma-1)}\big[\gamma\ \text{f}(\text{V}_0)+\text{V}_0\text{f}\ '(\text{V}_0)\big]$$\big(\because\ \text{f}(\text{V}_0)=\text{P}_0\big)$

$\Big(\frac{\text{dQ}}{\text{dV}}\Big)_{\text{V}-\text{V}_0}=\frac{1}{\gamma-1}$$\big[\gamma\ \text{P}_0+\text{V}_0\text{f}\ '(\text{V}_0)\big]$

$\therefore\ \Big(\frac{\text{dQ}}{\text{dV}}\Big)_{\text{V}-\text{V}_0}>1\therefore\ \text{and}\ \gamma>1\ \text{so}\ \frac{1}{\gamma-1}\text{is}+\text{ve}$

$\therefore\ \gamma\text{P}_0+\text{V}_0\text{f}\ '(\text{V}_0)>0$

$\text{V}_0\text{f}\ '(\text{V}_0)>-\gamma\text{P}_0$

$\text{f}\ '(\text{V}_0)>\frac{-\gamma\text{P}_0}{\text{V}_0}$

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Question 75 Marks
A person of mass 60kg wants to lose 5kg by going up and down a 10m high stairs. Assume he burns twice as much fat while going up than coming down. If 1kg of fat is burnt on expending 7000 kilo calories, how many times must he go up and down to reduce his weight by 5kg?
Answer
Gravitational potential energy (PE) of an object at height (h) is mgh. The energy losses by person in the form of fat will be utilised to increase PE of the person. As it is given that he burns twice as much fat while going up than coming down. Thus, the calorie consumed by the person in going up is mgh, and calorie consumed by the person in comming down is 1/ 2 mgh

According to the problem, height of the stairs  = h = 10 m 

Work done to burn 5kg of fat 

= (5kg) (7000 × 103 cal) (4.2J/ cal)

= 147 × 106J

Work done towards burning of fat in one trip (up and down the stairs )

$=\text{mgh}+\frac{1}{2}\text{mgh}=\frac{3}{2}\text{mgh}$

$=\frac{3}{2}(60\text{kg})(10\text{m/ s}^2)(10m)=9\times10^3\text{J}$

(as only half the work done while coming down is useful in burning fat ) 

$\therefore$ Number of times, the person has to go up and  down the stairs (no. of trips required)

$\text{N}=\frac{147\times10^6\text{J}}{9\times10^3\text{J}}=16.3\times10^3\text{times}$

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