Question types

Alcohols, Phenols and Ethers question types

72 questions across 6 question groups — pick any mix to generate a Chemistry paper with step-by-step answer keys.

72
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Sample Questions

Alcohols, Phenols and Ethers questions

One sample from each question group in this chapter. Select any group above to see the full set with answer keys.

Lucas reagent is:
  • Anhydrous $ CaCl_{2} $ and conc. HCl
  • B
    Anhydrous $ ZnCl_{2} $ and conc. HCl
  • C
    Anhydrous $ AlCl_{3} $ and conc. HCl
  • D
    Anhydrous $ PdCl_{2} $ and conc. HCl

Answer: A.

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Predict the reagent for carrying out the following conversions :
(i) Phenol to benzoquinone
(ii) Anisole to p-bromoanisole
(iii) Phenol to 2, 4, 6-tribromophenol
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Q 173 Marks Question3 Marks
(a) Out of t-butyl alcohol and n-butanol, which one will undergo acid catalysed dehydration faster and why?
(b) Carry out the following conversions :
(i) Phenol to Salicylaldehyde
(ii) t-butylchloride to t-butyl ethyl ether
(iii) Propene to Propanol
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What happens when :
(a) Ethene is passed into concentrated $H _2 SO _4$ and the product boiled with water.
(b) Ethyl ethanoate is boiled with KOH aq.
(c) Methyl magnesium iodide is heated with methanol.
(d) Acetaldehyde is heated with Tollen's reagent.
(e) Alkaline solution of phenol is heated with $CO _2$ under high pressure and then the product is acid hydrolysed.
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What happens when:
(a) Propene is passed into concentrated $H _2 SO _4$ and the product is boiled with water.
(b) Methoxy ethane is heated with HI.
(c) Ethanol is heated with Fenton's reagnet.
(d) Toluene is heated with Chromyl Chloride in $CS _2$ and the product is hydrolysed.
(e) Crotonaldehyde is treated with $LiAH _4 / dry$ ether and the product is acid hydrolysed.
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Write equations of the following reactions :
(i) Friedel Crafts reaction-alkylation of anisole.
(ii) Nitration of anisole.
(iii) Bromination of anisole in ethanoic acid medium.
(iv) Friedel Crafts acetylation of anisole.
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Explain giving reasons :
(i) Alcohols are generally soluble in water.
(ii) Phenols boil at higher temperature than arenes of comparable molecular mass.
(iii) The lower homologues of alcohols are soluble in water whereas phenols are slightly soluble in water.
(v) Boiling point of an alcohol is higher than the corresponding alkane.
(vi) The solubility of alcohols in water decreases with increase in molecular mass.
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Give equations for the following reactions :
(i) Oxidation of propan-1-ol with alkaline $KMnO _4$ solution.
(ii) Bromine in presence of $C S _{ 2 }$ with phenol.
(iii) Dilute nitric acid with phenol.
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What happens when primary, secondary and tertiary alcohols are:
(i) Oxidised using acidified potassium permanganate.
(ii) Passed over heated copper at 570 K.
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