- AEthane
- ✓Acetylene
- CEthylene
- DMethane
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| Catalyst | Process |
| $(i) \;\mathrm{Na}_{2} \mathrm{O}$ | $(a)$ The oxidation of ethyne to ethanal |
| $(ii) \;\mathrm{TiCl}_{4}+ \mathrm{Al(CH_3)}_{3}$ | $(b)$ Polymerisation of alkynes |
|
$(iii)\;\mathrm{PdCl_2} $ |
$(c)$ Oxidation of $SO_2$ in the manufacture of $H_2SO_4$ |
| $(iv)\;$Nickel complexes | $(d)$ Polymerisation of ethylene |
Which of the following is the correct option ?

$\Delta_f G^0[\mathrm{C}(\text { graphite })]=0 \mathrm{kJmol}^{-1}$
$\Delta_f G^0[\mathrm{C}(\text { diamond })]=2.9 \mathrm{kJmol}^{-1}$
The standard state means that the pressure should be $1$ bar, and substance should be pure at a given temperature. The conversion of graphite [C(graphite)] to diamond [C(diamond)] reduces its volume by $2 \times 10^{-6} \mathrm{~m}^3 \mathrm{~mol}^{-1}$. If $\mathrm{C}$ (graphite) is converted to $\mathrm{C}$ (diamond) isothermally at $\mathrm{T}=298 \mathrm{~K}$, the pressure at which $C$ (graphite) is in equilibrium with C(diamond), is
[Useful information: $1 \mathrm{~J}=1 \mathrm{~kg} \mathrm{~m}^2 \mathrm{~s}^{-2} ; 1 \mathrm{~Pa}=1 \mathrm{~kg} \mathrm{~m}^{-1} \mathrm{~s}^{-2} ; 1 \mathrm{bar}=10^5 \mathrm{~Pa}$ ]