MCQ
$50\, mL$ of $0.1\, M$ solution of a salt reacted with $25\, mL$ of $0.1\, M$ solution of sodium sulphite. The half reaction for the oxidation of sulphite ion is

$SO{{_{3}^{2-}}_{\left( aq. \right)}}+{{H}_{2}}{{O}_{\left( l \right)}}\to SO{{_{4}^{2-}}_{\left( aq. \right)}}+2{{H}^{+}}_{\left( aq. \right)}+2{{H}^{+}}_{\left( aq. \right)}+2{{e}^{-}}$

If the oxidation number of metal in the salt was $+3$, what would be the new oxidation number of metal?

  • A
    $0$
  • B
    $1$
  • $2$
  • D
    $4$

Answer

Correct option: C.
$2$
c
Meq. of sodium sulphite $=$ Meq. of salt

$25 \times 0.1 \times 2=50 \times 0.1 \times \mathrm{n}$

$\therefore \quad \mathrm{n}=1$

(where $\mathrm{n}$ represents valence factor for metal involving no. of electrons gained)

Thus $\mathrm{M}^{3+}+\mathrm{e} \longrightarrow \mathrm{M}^{2+}$

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