A solid expands upon heating because
KVPY 2014, Diffcult
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(a)

Potential energy versus separation plot for two atoms in a solid is as shown below.

From above graph, we see that as temperature rises $\left(T_3 > T_2 > T_1\right)$, total energy of atoms also increases $\left(E_3 > E_2 > E_1\right)$

As a result, mean separation between atoms also increases $\left(r_3 > r_2 > r_1\right)$.

Hence, crystalline solids in general expands on heating.

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