Hybridization of $\mathrm{Si}-\mathrm{s} p^{3},$ bond angle $=109\,^o28'$
$\angle Cl-\text{N}-\text{Cl}$ in $NCl_3$ is greater than $\angle \text{Cl}-\text{P}-\text{Cl}$ in $\mathrm{PCl}_{3}$ because partidpation of $s-$ orbital in the hybridization decreases from $NCl_3$ to $PCl_3$
Figure $(2)$
$\angle \text{Cl}-\text{P}-\text{Cl}$ in $\text{PC}{{\text{l}}_{3}}>\angle \text{H}-\text{Sb}-\text{H}$ in $\mathrm{SbH}_{3},$ as in $\mathrm{SbH}_{3}$, bond pairs are formed by overlapping of almost pure $p-$ orbitals.
$\angle \text{H}-\text{Sb}-\text{H}$ in $\text{Sb}{{\text{H}}_{3}}<\angle \text{H}-\text{Te}-\text{H}$ in $\mathrm{H}_{2}Te$ because two lone pairs are present on $Te$ while at $\mathrm{Sb}$ there is one lone pair.
સુચિ$-I$ ઓકસાઈડ | સુચિ$-II$ બંધનો પ્રકાર |
$A$ $N _2 O _4$ | $I$. $1 N = O$ બંધ |
$B$ $NO _2$ | $II$. $1 N - O - N$ બંધ |
$C$ $N _2 O _5$ | $III$. $1 N - N$ બંધ |
$D$ $N _2 O$ | $IV$. $1 N = N / N \equiv N$ બંધ |
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