In Balmer series \(n_1=2\) & \(n_2=3,4,5....\)
Last line of the spectrum is called series limit.
Limiting line is the line of shortest wavelength and high enegry when \({n_2} = \infty \)
\(\therefore \,\bar v = \frac{1}{\lambda } = \frac{{{R_H}}}{{n_1^2}} = \frac{{3.29 \times {{10}^{15}}}}{4}\)
\(= 8.22 \times 10^{14}\,s^{-1}\)
વિધાન $2$ : મુખ્ય કવૉન્ટમ આંક $(n)$ એ ઇલેકટ્રોનનું કેન્દ્રથઈ અંતર દર્શાવે છે.