Question
Describe the physical properties of amines.

Answer

SELF

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Explain the collision principle of any chemical reaction.
Attempt any five of the following:
(a) Aldopentoses named ribose and 2-deoxyribose are found in nucleic acids. What is their relative configuration?
(b) What are the three components of nucleic acids?
(c) Name the sugar present in milk. How many monosaccharide units are present in it? What are such oligosaccharides called?
(d) Is nucleotide and nucleoside the same? What are their roles?
(e) Why cannot vitamin C be stored in our body?
(f) During curdling of milk, what happens to sugar present in it?
(g) Account for the following:
a. There are 5-OH groups in glucose.
b. Glucose is a reducing sugar
A solution containing 30 g of non-volatile solute exactly in 90 g of water has a vapour pressure of 2.8 kPa at 298 K. Further, 18 g of water is then added to the solution and the new vapour pressure becomes 2.9 kPa at 298 K. Calculate :
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(ii) vapour pressure of water at 298 K
Draw all the isomers (geometrical and optical) of :
(i) $\left[ CoCl _2( en )_2\right]^{+}$
(ii) $\left[ Co \left( NH _3\right) Cl ( en )_2\right]^{2+}$
(iii) $\left[ Co \left( NH _3\right)_2 Cl _2( en )\right]^{+}$
  1. What type of deviation is shown by a mixture of ethanol and acetone? Give reason.
  2. A solution of glucose (molar mass = 180 g mol–1) in water is labelled as 10% (by mass). What would be the molality and molarity of the solution?

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Explain the open chain structure of glucose.
  1. What may be the possible oxidation states of the transition metals with the following d electronic configurations in the ground state of their atoms:

3d34s2, 3d54s2 and 3d6 4s3. Indicate relative stability of oxidation states in each case.

  1. Write steps involved in the preparation of (i) Na2CrO4 from chromite ore and (ii) K2MnO4 from pyrolusite ore.
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The following data were obtained during the first order thermal decomposition of SO2Cl2 at a constant volume.
$SO _2 Cl _2(g) \rightarrow SO _2(g)+ Cl _2(g)$
Experimenttime/s-1Total pressure/atm
100.5
21000.6
Calculate the rate of the reaction when total pressure is 0.65 atm.
Using crystal field theory, draw energy level diagram, write electronic configuration of the central metal atom/ion and determine the magnetic moment value in the following:
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  2. $[\text{FeF}_6]^{3-}, [\text{Fe(H}_2\text{O})_6]^{2+}, [\text{Fe(CN})_6]^{4-}$