$\begin{gathered}
\begin{array}{*{20}{c}}
{O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{C{H_3} - {\text{ }}C - {\text{ }}O - H\xrightarrow{{NaH{{\mathop {CO}\limits^{14} }_3}}}\mathop {(A)}\limits_{(gas)} \xrightarrow[{(ii){H_3}{O^ \oplus }}]{{(i)PhMgBr}}(B)}
\end{array} \hfill \\
\begin{array}{*{20}{c}}
{O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{C{H_3} - S - O - H\xrightarrow{{NaH\mathop {C{O_3}}\limits^{14} }}\mathop {(C)}\limits_{(gas)} \xrightarrow[{(ii){H_3}{O^ \oplus }}]{{(i)PhMgBr}}(D)} \\
{||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array} \hfill \\
\end{gathered}$

ઉપરોક્ત પ્રકિયા માં નીપજ $(B)$ અને $(D) $ શું હશે ?

Question

$\begin{gathered}
\begin{array}{*{20}{c}}
{O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{C{H_3} - {\text{ }}C - {\text{ }}O - H\xrightarrow{{NaH{{\mathop {CO}\limits^{14} }_3}}}\mathop {(A)}\limits_{(gas)} \xrightarrow[{(ii){H_3}{O^ \oplus }}]{{(i)PhMgBr}}(B)}
\end{array} \hfill \\
\begin{array}{*{20}{c}}
{O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{C{H_3} - S - O - H\xrightarrow{{NaH\mathop {C{O_3}}\limits^{14} }}\mathop {(C)}\limits_{(gas)} \xrightarrow[{(ii){H_3}{O^ \oplus }}]{{(i)PhMgBr}}(D)} \\
{||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array} \hfill \\
\end{gathered}$

ઉપરોક્ત પ્રકિયા માં નીપજ $(B)$ અને $(D) $ શું હશે ?

A$\begin{array}{*{20}{c}} {O\,\,\,\,\,\,\,\,\,} \\ {||\,\,\,\,\,\,\,\,\,\,} \\ {Ph - C - O - H,\,} \end{array}$ $\begin{array}{*{20}{c}} O \,\,\,\,\,\,\,\,\,\\ {||} \,\,\,\,\,\,\,\,\,\\ {Ph - S - O - H} \\ {||}\,\,\,\,\,\,\,\,\, \\ O\,\,\,\,\,\,\,\,\, \end{array}$
B$\begin{array}{*{20}{c}} {O\,\,\,\,\,\,\,\,\,\,\,}\\ {||\,\,\,\,\,\,\,\,\,\,\,}\\ {Ph - \mathop C\limits_{14} - O - H,\,} \end{array} $ $\begin{array}{*{20}{c}} {O\,\,\,\,\,\,}\\ {||\,\,\,\,\,\,\,}\\ {Ph - S - O - H} \end{array}$
C$\begin{array}{*{20}{c}} {O\,\,\,\,\,\,\,\,\,\,\,}\\ {||\,\,\,\,\,\,\,\,\,\,\,}\\ {Ph - \mathop C\limits_{14} - O - H,\,} \end{array} $ $\underset{14}{\mathop{\begin{matrix} O\,\,\,\,\,\, \\ ||\,\,\,\,\,\,\, \\ Ph-C-O-H \\ \end{matrix}}}\,$
D$\begin{matrix} \,\,\,\,\,\,\,\,O\,\,\,\,\,\,\,\, \\ \,\,\,\,\,\,||\,\,\,\,\,\,\,\, \\ Ph-\text{ }C-OH, \\ \end{matrix}$ $\begin{array}{*{20}{c}} {O\,\,\,\,\,\,}\\ {||\,\,\,\,\,\,\,}\\ {Ph - S - O - H} \end{array}$

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Solution

c

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