\(2 \rightarrow 3 \Rightarrow \text { Isochoric process }\)
\(3 \rightarrow 1 \Rightarrow \text { Isothermal process }\)
\(W = W _{1 \rightarrow 2}+ W _{2 \rightarrow 3}+ W _{3 \rightarrow 1}\)
\(=\left(- P \left( V _2- V _1\right)+0\left[- P _1 V _1 \ln \left(\frac{ V _2}{ V _1}\right)\right]\right)\)
\(=\left[-1 \times(40-20)+0+\left[-1 \times 20 \ln \left(\frac{20}{40}\right)\right]\right]\)
\(=-20+20 \ln 2\)
\(=-20+20 \times 2.3 \times 0.3\)
\(=-6.2 \text { bar } L\)
\(| W |=6.2 \text { bar } 1=620\,J\)
$(i)\,\,C\,({\rm{graphite}})\, + \,{O_2}{\kern 1pt} (g)\, \to \,C{O_2}\,(g);\,\Delta r{H^\circleddash} = x\,\,kJ\,mo{l^{ - 1}}$
$(ii)\,\,C\,({\rm{graphite}})\, + \,\frac{1}{2}{O_2}{\kern 1pt} (g)\, \to \,CO\,(g);\,\Delta r{H^\circleddash} = y\,\,kJ\,mo{l^{ - 1}}$
$(iii)\,\,CO\,(g)\, + \,\frac{1}{2}{O_2}{\kern 1pt} (g)\, \to \,C{O_2}\,(g);\,\Delta r{H^\circleddash} = z\,\,kJ\,mo{l^{ - 1}}$
ઉપરોક્ત, ઊષ્મારાસાયણિક સમીકરણો ના આધારે નીચેનામાંથી ક્યો બીજગણિતિક સંબંધ સાચો છે?