Question
Explain Bayer’s process of concentration of bauxite with a chemical equation.

Answer

1. Bauxite is the main ore of aluminium with silica $\left( SiO _2\right)$, ferric oxide $\left( Fe _2 O _3\right)$ and titanium oxide $\left( TiO _2\right)$ as impurities in it.
2. In this process, the bauxite ore is first crushed and then it is leached by heating with hot concentrated caustic soda $( NaOH )$ solution under high pressure for 2 to $8 hrs$ at 140 to $150^{\circ} C$ in a tank called a digester.
3. Aluminium oxide, being amphoteric in nature, dissolves in an aqueous $NaOH$ solution, forming water-soluble sodium aluminate.
$
\underset{\substack{\text { Aluminium } \\ \text { oxide }}}{ Al _2 O _3 \cdot 2 H _2 O _{( s )}}+\underset{\substack{\text { Sodium } \\ \text { hydroxide }}}{ NaOH _{( aq )}} \longrightarrow \underset{\substack{\text { Sodium } \\ \text { aluminate }}}{2 NaAlO _{2( aq )}}+\underset{\text { Water }}{3 H _2 O _{( l )}}
$
4. The iron oxide present in the gangue does not dissolve in an aqueous $NaOH$ solution and is separated by filtration.
5. However, silica from the gangue dissolves in an aqueous $NaOH$ solution forming water-soluble sodium silicate.
6. The solution of sodium aluminate is diluted with water and then cooled to $50^{\circ} C$. This gives aluminium hydroxide as a precipitate.
$
\underset{\substack{\text { Sodium } \\ \text { aluminate }}}{ NaAlO _{2( aq )}}+\underset{\text { Water }}{2 H _2 O _{( l )}} \longrightarrow \underset{\substack{\text { Sodium } \\ \text { hydroxide }}}{ NaOH _{( aq )}}+\underset{\substack{\text { Aluminium } \\ \text { hydroxide }}}{ Al ( OH )_3 \downarrow}
$
7. The aluminium hydroxide is then filtered, washed, dried and calcined by heating at $1000{ }^{\circ} C$ to get pure aluminium oxide, called alumina.
$\underset{\substack{\text { Aluminium } \\ \text { hydroxide }}}{2 Al ( OH )_{3( s )}} \stackrel{\text { heat }}{1000^{\circ} C } \underset{\substack{\text { Aluminium } \\ \text { oxide }}}{ Al _2 O _{3( s )}}+\underset{\text { Water vapour }}{3 H _2 O _{( g )}}$

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