This law states that "The amount of a substance deposited or dissolved at an electrode is directly proportional to the charge passing through the electrolytes.
Faraday's second law: This law states that the amounts of different substances deposited at electrodes by passage of the same quantity of electricity are proportional to their chemical equivalent(\(E\)).
$Mn^{2+} +2e- \rightarrow Mn;\, E^o = -1.18\,V$
$2(Mn^{3+} +e^- \rightarrow Mn^{2+} )\,;\,E^o=+1.51\,V$
તો $3Mn^{2+} \rightarrow Mn+ 2Mn^{3+}$ માટે $E^o$ કેટલો થશે ?
(ઝિંકનું પરમાણવીય દળ = $65.4 \mathrm{amu}$ )
${[Fe\,{(CN)_6}]^{4 - }}\, \to \,{[Fe{(CN)_6}]^{3 - }}\, + \,{e^ - }\,;\,$ ${E^o}\, = \, - \,0.35\,V$
$\,F{e^{2 + }}\, \to \,F{e^{3 + }}\, + \,{e^ - }\,;$ ${E^o}\, = \, - \,0.77\,V$