MCQ
For a spontaneous reaction the $\Delta G,$ equilibrium constant $ (K)$ and $E_{Cell}^o$ will be respectively
- ✓$ - ve,\, > 1,\, + ve$
- B$ + ve,\, > 1,\, - ve$
- C$ - ve,\, < 1,\, - ve$
- D$ - ve,\, > 1,\, - ve$
We know for a spontaneous reaction
$\Delta G \,<\,0 \text {. }$
$\therefore- RT \ln K \,<\,0$
$\therefore \ln K\,>\,0$
$\therefore K\,>\,1$
and $- nF E ^{\circ}<0$
$\therefore E _{\text {cell }}^{\circ}\,>\,0$
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| Complexes | No. of unpaired electron | ||
| $A$ | $[CrF_6]^{-4}$ | $P$ | $5$ |
| $B$ | $[MnF_6]^{-4}$ | $Q$ | $2$ |
| $C$ | $[Cr(CN)_6]^{-4}$ | $R$ | $1$ |
| $D$ | $[Mn(CN)_6]^{-4}$ | $S$ | $4$ |
$(I)\, [Co(NO_2)_3(NH_3)_3]$
$(II)$ cis $-[ RhCl_2 (NH_3)_4]^+$
$(III)\, [Cr(OX)_3]^{-3}$
$(IV)$ cis $ -[PtCl_2 (en)]$
$(V)$ trans $-[Cr(en)_2 Br_2]^+$
$(VI)$ cis $-[Cr(en)_2 Br_2]^+$
