Question
From where does ozone come in the photochemical smog?

Answer

When fossil fuels are burnt, nitric oxide and hydrocarbons from unburnt fuels are produced. In sunlight, nitric oxide is converted to nitrogen dioxide. $\mathrm{NO}_2$ absorbs energy from sunlight and breaks up into NO and free oxygen atoms which are very reactive and combine with $\mathrm{O}_2$ to form $\mathrm{O}_3$, which reacts with NO to form $\mathrm{NO}_2$ and $\mathrm{O}_2$.
$\text{NO}_2\xrightarrow{ \ \ \ \ \text{h}\upsilon\ \ \ }\text{NO}+\text{O}$
$\text{O}+\text{O}_2+\rightleftharpoons\text{O}_3$
$\text{NO}+\text{O}_3\xrightarrow{ \ \ \ \ \ \ \ }\text{NO}_2+\text{O}_2$

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