Given below are two statements : Statement I : A homolepitc octah… - Vidyadip

MCQ

Given below are two statements :
Statement I : A homolepitc octahedral complex, formed using monodentate ligands, will not show stereoisomerism.
Statement II : cis- and trans- platin are heteroleptic complexes of Pd .
In the light of the above statements, choose the correct answer from the options given below.

A
Both statement I and Statement II are false.
B
Statement I is false but Statement II is true.
C
Both statement I and Statement II are true.
✓
Statement I is true but Statement II is false.

✓

Answer

Correct option: D.

Statement I is true but Statement II is false.

(D) Statement I is true but Statement II is false.
Homoleptic complex of type $\left[\mathrm{Ma}_{6}\right]$ (Where $\mathrm{a} \Rightarrow$ monodentate ligand) cannot show geometrical as well as optical isomerism.
Cis-platin and trans-platin has formula $\left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{2} \mathrm{Cl}_{2}\right]$ which is a heteroleptic complex of platinum.

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