| Column $I$ | Column $II$ |
| $(A)$ $Image$ | $(p)$ Racemic mixture |
| $(B)$ $Image$ | $(q)$ Addition reaction |
| $(C)$ $Image$ | $(r)$ Substitution reaction |
| $(D)$ $Image$ | $(s)$ Coupling reaction |
| $(t)$ Carbocation intermediate |

(image) $\xrightarrow[{N{H_4}Cl}]{{Zn}}.....?$
$\begin{matrix}
\begin{matrix}
\,\,\,\,\,C{{H}_{3}} \\
| \\
\end{matrix}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
C{{H}_{3}}-C-C{{H}_{2}}C{{H}_{2}}OH \\
|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
C{{H}_{3}}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
\end{matrix}$ $\xrightarrow[{{H_2}O,heat}]{{{K_2}C{r_2}{O_7};{H_2}S{O_4}}}A$ $\xrightarrow{{SOC{l_2}}}B\xrightarrow[{(2{\kern 1pt} mole)}]{{{{(C{H_3})}_2}NH}}C$ $\xrightarrow[{2.{\kern 1pt} {H_2}O}]{{\begin{array}{*{20}{c}}
{1.{\kern 1pt} LiAl{H_4}} \\
{diethyl{\kern 1pt} {\kern 1pt} ether}
\end{array}}}D$
Statement $I$: Aniline reacts with con. $\mathrm{H}_2 \mathrm{SO}_4$ followed by heating at $453-473 \mathrm{~K}$ gives $\mathrm{p}$ aminobenzene sulphonic acid, which gives blood red colour in the 'Lassaigne's test'.
Statement $II$: In Friedel - Craft's alkylation and acylation reactions, aniline forms salt with the $\mathrm{AlCl}_3$ catalyst. Due to this, nitrogen of aniline aquires a positive charge and acts as deactivating group.
In the light of the above statements, choose the correct answer from the options given below :