MCQ
In which of the following system, doubling the volume of the container cause a shift to the right
  • A
    ${H_2}_{(g)} + C{l_2}_{(g)} $ $\rightleftharpoons$ $ 2HCl_{(g)}$
  • B
    $2CO_{(g)} + {O_2}_{(g)}  $ $\rightleftharpoons$ $ 2C{O_2}_{(g)} $
  • C
    ${N_2}_{(g)}  + 3{H_2}_{(g)}  $ $\rightleftharpoons$ $ 2N{H_3}_{(g)} $
  • $PC{l_5}_{(g)} \rightleftharpoons PC{l_3}_{(g)} + C{l_2}_{(g)}$

Answer

Correct option: D.
$PC{l_5}_{(g)} \rightleftharpoons PC{l_3}_{(g)} + C{l_2}_{(g)}$
(d)Increase in volume, i.e., decrease in pressure shifts the equilibrium in the direction in which number of moles increases ($\Delta$ $n$ positive)

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