In Williamson synthesis of mixed ether having a primary and a ter… - Vidyadip

MCQ

In Williamson synthesis of mixed ether having a primary and a tertiary alkyl group if tertiary halide is used, then

A
Rate of reaction will be slow due to slow cleavage of carbon-halogen bond.
✓
Alkene will be the main product
C
Simple ether will form instead of mixed ether.
D
Expected mixed ether will be formed.

✓

Answer

Correct option: B.

Alkene will be the main product

b
The tertiary alkylhalide undergo elimination reaction to give alkenes

$\begin{array}{*{20}{c}}
{\,\,\,\,\,\begin{array}{*{20}{c}}
{\,\,\,\,C{H_3}\,\,} \\
{|\,\,\,\,}
\end{array}} \\
{C{H_3} - C - X + } \\
{\,\,\,\,\,|\,\,\,\,} \\
{\,\,\,\,\,\,\,\,\,C{H_3}\,\,\,}
\end{array}$ $NaOC_2H_5\,\to $ $\mathop {\begin{array}{*{20}{c}}
{\,\,\,\,\,C{H_3}} \\
{|\,} \\
{C{H_3} - C = C{H_2}}
\end{array}}\limits_{2\, - \,methyl\,propane} $

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