$\left| {\begin{array}{*{20}{c}}
{1 + {{\cos }^2}\theta }&{{{\sin }^2}\theta }&{4\cos 6\theta }\\
{{{\cos }^2}\theta }&{1 + {{\sin }^2}\theta }&{4\cos 6\theta }\\
{{{\cos }^2}\theta }&{{{\sin }^2}\theta }&{1 + 4\cos 6\theta }
\end{array}} \right| = 0$
${R_2} \to {R_2} - {R_1},{R_3} \to {R_3} - {R_1}$
$ \Rightarrow \left| {\begin{array}{*{20}{c}}
{1 + {{\cos }^2}\theta }&{{{\sin }^2}\theta }&{4\cos 6\theta }\\
{ - 1}&1&0\\
{ - 1}&0&1
\end{array}} \right| = 0$
${C_1} \to {C_1} + {C_2}$
$ \Rightarrow \left| {\begin{array}{*{20}{c}}
2&{{{\sin }^2}\theta }&{4\cos 6\theta }\\
0&1&0\\
{ - 1}&0&1
\end{array}} \right| = 0$
expanding along first column
$ \Rightarrow 2\left[ {1 - 0} \right] - 1\left[ { - 4\cos 6\theta } \right] = 0$
$ \Rightarrow 2 + 4\cos 6\theta = 0$
$ \Rightarrow \cos 6\theta = - \frac{1}{2}$
$ \Rightarrow 6\theta = \frac{{2\pi }}{3}$
$ \Rightarrow \theta = \frac{\pi }{9}$