કોપર $(II)$ નો અષ્ટફલકીય સંકિર્ણ બંધારણીય વિકૃતી પામે છે. (જોન ટેલર). નીચે આપેલા કોપર $(II)$ સંકિર્ણો પૈકી કયો સૌથી મહતમ બંધારણીય વિકૃતી દર્શાવશે. $(en -$ ઈથીલીન ડાયએમાઈન; $\left.H _2 N - CH _2- CH _2- NH _2\right)$
JEE MAIN 2022, Medium
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a There is unsymmetric filling of $e_{g}$ subset of $Cu ^{+2} \;ion$, while there is symmetrical distribution in $t _{2 g }$ set, if the complex has same ligand there will be equal repulsion which leads to symmetrical bond length along $t _{2 g }$ , but due to uneven filling of electron in $e _{ g }$ subset, either octahedral will be elongated or compressed.
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