\(Ca_3(PO_4)_2\rightleftharpoons 3Ca^{2+} + 2PO_4^{3-}\) \(k_{sp}=(3S)^3\times (2S)^2=108s^5\) \(\therefore \,\,s\, = \,\,{\left( {\frac{{{K_{sp}}}}{{108}}} \right)^{1/5}}\)
\(Hg_2Cl_2\rightleftharpoons Hg_2^{2+}+2Cl^-\) \(k_{sp} = S \times (2s)^2 = 4s^3\) \(\therefore \,\,\,s\,\, = \,\,{\left( {\frac{{{K_{sp}}}}{4}} \right)^{1/3}}\)
\(Ag_3PO_4 \rightleftharpoons 3Ag^++PO_4^{3-}\) \(k_{sp} = (3s)^3 \times s = 27s^4\) \(\therefore \,\,s\,\, = \,\,{\left( {\frac{{{K_{sp}}}}{{27}}} \right)^{1/4}}\)
\(Cus \rightleftharpoons Cu^{2+}+s^{2-} \,\,,k_{sp}=s^2\) \(\therefore \,\,s\,\, = \,\,\sqrt {ksp} \)
સૂચી $-I$ (ધનઆયનો) | સૂચી $-II$(સમૂહ પ્રક્રિયકો) |
$P \rightarrow Pb ^{2+}, Cu ^{2+}$ | $(i)$ $H _2 S$ gas in presence of dilute $HCl$ |
$Q \rightarrow Al ^{3+}, Fe ^{3+}$ | $(ii)$ $\left( NH _4\right)_2 CO _3$ in presence of $NH _4 OH$ |
$R \rightarrow Co ^{2+}, Ni ^{2+}$ | $(iii)$ $NH _4 OH$ in presence of $NH _4 CI$ |
$S \rightarrow Ba ^{2+}, Ca ^{2+}$ | $(iv)$ $H _2 S$ in presence of $NH _4 OH$ |