\(Pb ^{4+}+4 e ^{-} \rightarrow Pb \quad \Delta G _2^0=-4 FE _2^0\)
\(Pb ^{2+} \rightarrow Pb ^{4+}+2 e ^{-} \quad \Delta G _3^0=-2 FE _3^0\)
\(\Delta G _3^0=\Delta G _1^0-\Delta G _2^0\)
\(-2 FE _3^0=2 F (2 n - m )\)
\(E _3^0= m -2 n = m - xn\)
Hence \(x=2\)
(આપેલ : $E _{ Zn ^{2+} \mid Zn }^{ o }=-0.763 V , E _{ Sn ^{x+} \mid Sn }^{ O }=+0.008 V$ ધારી લો $\frac{2.303 RT }{ F }=0.06\, V$ )
$2AgCl(s) + H_2(g) \rightarrow 2Ag(s) + 2H^{+} + 2Cl^{-}$ એ $G^o$ કેટલો થશે?
$[\Lambda_{\mathrm{H}^{+}}^{\circ}=350 \,\mathrm{~S}\, \mathrm{~cm}^{2}\, \mathrm{~mol}^{-1},\Lambda_{\mathrm{CH}_{3} \mathrm{COO}^{-}}^{\circ}=50\, \mathrm{~S}\, \mathrm{~cm}^{2}\, \mathrm{~mol}^{-1}]$
$Mn^{2+} + 2e^- \rightarrow Mn,\, $$E^o = - 1.18\, V$
$Mn^{2+} \rightarrow Mn^{3+} + e^-,$ $ E^o = - 1.51 \,V$
તો પ્રક્યિા $3Mn^{2+} \rightarrow Mn^o + 2Mn^{3+},$ માટે $E^o$ તથા પુરોગામી પ્રક્રિયાની શક્યતા અનુક્રમે .... થશે.