Magnetic moment, \(\mu=\sqrt{n(n+2)}\)
Where, \(n=\) number of unpaired electrons
The electronic configuration for the given ions is as follow:
For \(M n^{2+}[Z=25]=1 s^{2}, 2 s^{2}, 2 p^{6}, 3 s^{2} 3 p^{6}, 3 d^{2} 4 s^{0}\)
\(\mathop {\boxed \uparrow \boxed \uparrow \boxed \uparrow \boxed \uparrow \boxed \uparrow }\limits^{3{d^2}} \)
\(\mu=\sqrt{5(5+2)}=\sqrt{35}\)
For \(C r^{2+}[Z=24]=1 s^{2}, 2 s^{2} 2 p^{6}, 3 s^{2} 3 p^{6}, 3 d^{4}, 4 s^{0}\)
\(\mathop {\boxed \uparrow \boxed \uparrow \boxed \uparrow \boxed \uparrow }\limits^{3{d^4}} \)
\(\mu=\sqrt{4(4+2)}=\sqrt{24}\)
For \(T i^{2+}[Z=22]=1 s^{2}, 2 s^{2} 2 p^{6}, 3 s^{2} 3 p^{6}, 3 d^{2}, 4 s^{0}\)
\(\mathop {\boxed \uparrow \boxed \uparrow \boxed \uparrow }\limits^{3{d^2}} \)
\(\mu=\sqrt{2(2+2)}=\sqrt{8}\)
\(\therefore\) correct order of spin only magnetic moment is
\(M n^{2}+C r^{2+}>T i^{2+}\)
સૂચિ-$I$ (સંકીર્ણ આયન) |
સૂચિ$II$ ($M.B.$માં સ્પીન ફક્ત ચુંબકીય ચાક્માત્રા) |
$A$ ${\left[\mathrm{Cr}\left(\mathrm{NH}_5\right)_0\right]^{3+}}$ | $I$ $4.90$ |
$B$ ${\left[\mathrm{NiCl}_4\right]^{2-}}$ | $II$ $3.87$ |
$C$ ${\left[\mathrm{CoF}_6\right]^{3-}}$ | $III$ $0.0$ |
$D$ ${\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}}$ | $IV$ $2.83$ |
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