MCQ
On the basis of following equations the heat of dimerisation of $NO_2$ will be

$(i)\, N_2 + 2O_2 \to 2NO_2\,\,\, \Delta H = 67.9\,kJ$

$(ii)\, N_2 + 2O_2 \to N_2O_4\,\,\, \Delta H = 9.3\,kJ$

......$kJ$

  • A
    $+77.2$
  • B
    $-77.2$
  • $-58.6$
  • D
    $+58.6$

Answer

Correct option: C.
$-58.6$
c
$2 \mathrm{NO}_{2} \rightarrow \mathrm{N}_{2} \mathrm{O}_{4}, \Delta \mathrm{H}$

$\Delta \mathrm{H}_{2}-\Delta \mathrm{H}_{1}=\Delta \mathrm{H}$

$9.3-67.9=\Delta H$

$-58.6\, \mathrm{kJ}=\Delta \mathrm{H}$

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