Question
Read the passage given below and answer the following questions:
Carbohydrates are polyhydroxy aldehydes and ketones and those compounds which on hydrolysis give such compounds are also carbohydrates. The carbohydrates which are not hydrolysed are called monosaccharides. Monosaccharides with aldehydic group are called aldose and those which free ketonic groups are called ketose. Carbohydrates are optically active. Number of optical isomers $= 2^n$
Where $n =$ numberofasymmetric carbons. Carbohydrates are mainlysynthesised by plants during photosynthesis. The monosaccharides give the characteristic reactions of alcohols and carbonyl group (aldehydes and ketones). It has been found that these monosaccharides exist in the form of cyclic structures. In cyctization, the $-OH$ groups $($generally $C_5$ or $C_4$ in aldohexoses and $C_5$ or $C_6$ in ketohexoses$)$ combine with the aldehyde or keto group. As a result, cyclic structures of five or six membered rings containing one oxygen atom are formed, e.g., glucose forms a ring structure. Glucose contains one aldehyde group, one $IO$ alcoholic group and four $2^\circ$ alcoholic groups in its open chain structure.
The following questions are multiple choice questions. Choose the most appropriate answer:
  1. First member of ketos sugar is:
  1. Ketotriose.
  2. Ketotetrose.
  3. Ketopentose.
  4. Ketohexose.
  1. In $CH_2OHCHOHCHOHCHOHCHOHCHO$, the number of optical isomers will be:
  1. $16$
  2. $8$
  3. $32$
  4. $4$
  1. Some statements are given below:
  1. Glucose is aldohexose.
  2. Naturally occurring glucose is dextrorotatory.
  3. Glucose contains three chiral centres.
  4. Glucose contains one $1^\circ$ alcoholic group and four $2^\circ$ alcoholic groups.
Among the above, correct statements are:
  1. $1$ and $2$ only
  2. $3$ and $4$ only
  3. $1, 2$ and $4$ only
  4. $1, 2, 3$ and $4$
  1. Two hexoses fonn the same osazone, find the correct statement about these hexoses.
  1. Both of them must be aldoses.
  2. They are epimers at $C-3.$
  3. The carbon atoms $I$ and $2$ in both have the same configuration.
  4. The carbon atoms $3, 4$ and $5$ in both have the same configuration.
  1. Which of the following reactions of glucose can be explained only by its cyclic structure?
  1. Glucose forms cyanohydrin with HCN.
  2. Glucose reacts with hydroxylamine to form an oxime.
  3. Pentaacetate of glucose does not react with hydroxylamine.
  4. Glucose is oxidised by nitric acid to gluconic acid.

Answer

  1. (a) Ketotriose.
  1. (a) $16$
  1. (c) $1, 2$ and $4$ only
Explanation:

Glucose contains four chiral centres.
  1. (d) The carbon atoms $3, 4$ and $5$ in both have the same configuration.
Explanation:

In the formation of osazone, $C-1$ and $C-2$ react with phenylhydrazine to form phenylhydrazone. If $C-3, C-4, C-5$ have same configuration they will form same osazone even if they differ in configuration at $C-1$ or $C-2.$
  1. (c) Pentaacetate of glucose does not react with hydroxylamine.
Explanation:

Pentacetate of glucose does not react with hydroxylamine showing absence of free $-CHO$ group. This cannot be explained by open structure of glucose.

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In these questions (Q.No. i - iv), a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices.
  1. Assertion and reason both are correct statements and reason is correct explanation for assertion.
  2. Assertion and reason both are correct statements but reason is not correct explanation for assertion.
  3. Assertion is correct statement but reason is wrong statement.
  4. Assertion is wrong statement but reason is correct statement.
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Reason: It displaces other halogens from its aqueous solution.
Read the passage given below and answer the following questions:
The concentration of a solute is very important in studying chemical reactions because it determines how often molecules collide in solution and thus indirectly determine the rate of reactions and the conditions at equilibrium. There are several ways to express the amount of solute present in a solution. The concentration of a solution is a measure of the amount of solute that has been dissolved in a given amount of solvent or solution. Concentration can be expressed in terms of molarity, molality, parts per million, mass percentage, volume percentage, etc.
The following questions are multiple choice questions. Choose the most appropriate answer:
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  1. $1.95m, 0.120$
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  4. $3.0m, 0.0352$
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  2. $1.89$
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  1. Which of the following is correct relationship between mole fraction and molality?
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Read the passage given below and answer the following questions:
In an assembly of atoms or molecules, a solid phase is formed whenever the interatomic attractive forces significantly exceed the disruptive thermal forces and thus restrict the mobility of atoms, forcing them into more or less fixed positions. From energy considerations, it is evident that in such solids the atoms or molecules will always attempt to assume highly ordered structures which are characterised by symmetry. Depending on the nature of the active interatomic forces, all solids may be subdivided into the following categories :
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Covalent solids: In these solids, the constituent particles are atoms which are linked together by a continuous system of covalent bonds. These bonds are strong and directional in nature. The covalent crystals are hard, have high melting points, are poor conductors of electricity. Diamond is a typical example of covalent solids.
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In these questions (Q. No. i-iv), a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices.
  1. Assertion and reason both are correct statements, and reason is correct explanation for assertion.
  2. Assertion and reason both are correct statements, but reason is not correct explanation for assertion.
  3. Assertion is correct statement, but reason is wrong statement.
  4. Assertion is wrong statement, but reason is correct statement.
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Read the passage given below and answer the following questions:
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The following questions are multiple choice questions. Choose the most appropriate answer:
  1. Which of the following is most reactive towards nucleophilic substitution reaction?
  1. $C_6H_5Cl$
  2. $CH_2 = CHCl$
  3. $ClCH_2CH = CH_2$
  4. $CH_3CH = CHCl$
  1. Isopropyl chloride undergoes hydrolysis by:
  1. $S_N1$ mechanism.
  2. $S_N2$ mechanism.
  3. $S_N1$ and $S_N2$ mechanism.
  4. Neither $S_N1$ nor $S_N2$ mechanism.
  1. The most reactive nucleophile among the following is:
  1. $CH_3O^-$
  2. $C_6H_5O^-$
  3. $(CH_3)_2CHO^-$
  4. $(CH_3)_3CO^-$
  1. Tertiary alkyl halides are practically inert to substitution by $S_N2$ mechanism because of:
  1. Insolubility.
  2. Instability.
  3. Inductive effect.
  4. Stearic hindrance.
  1. Which of the following is the correct order of decreasing $S_N2$ reactivity?
  1. $RCH_2X > R_2CHX > R_3CX$
  2. $R_3CX > R_2CHX > RCH_2X$
  3. $R_2CHX > R_3CX > RCH_2X$
  4. $RCH_2X > R_3CX > R_2CHX$
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  1. Assertion and reason both are correct statements and reason is correct explanation for assertion.
  2. Assertion and reason both are correct statements but reason is not correct explanation for assertion.
  3. Assertion is correct statement but reason is wrong statement.
  4. Assertion is wrong statement but reason is correct statement.
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Reason: Rate constant also doubles.
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  1. Reason: The half-life time of a first order reaction is not always constant and it depends upon the initial concentration of reactants.
Reason: Acid only acts as a catalyst whereas alkali acts as one of the reactants.
  1. Assertion: For a first order reaction, the concentration of the reactant decreases exponentially with time.
Reason: Rate of reaction at any time depends upon the concentration of the reactant at that time.
  1. Assertion: Half-life period for a first order reaction is independent of initial concentration of the reactant.
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In these questions, a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices.
Assertion: The enthalpy of physisorption is lesser than chemisorption.
Reason: Molecules of adsorbate and adsorbent are held by van der Waal's forces in physisorption and by chemical bonds in chemisorption.
Read the passage given below and answer the following questions:
The addition reaction of enol or enolate to the carbonyl functional group of aldehyde or ketone is known as aldol addition. The $\beta-$ hydroxyaldehyde or $\beta-$hydroxyketone so obtained undergo dehydration in second step to produce a conjugated enone. The first part of reaction is an addition reaction and the second part is an elimination reaction. Carbonyl compound having $\propto-$hydrogen undergoes aldol condensation reaction.

The following questions are multiple choice questions. Choose the most appropriate answer:
  1. Condensation reaction is the reverse of which of the following reaction?
  1. Lock and key hypothesis.
  2. Oxidation.
  3. Hydrolysis.
  4. Glycogen formation.
  1. Which of the following compounds would be the main product of an aldol condensation of acetaldehyde and acetone?
  1. $CH_3CH = CHCHO$
  2. $CH_3CH = CHCOCH_3$
  3. $(CH_3)_2C = CHCHO$
  4. $(CH_3)_2C = CHCOCH_3$
  1. Which combination of carbonyl compounds gives phenyl vinyl ketone by an aldol condensation?
  1. Acetophenone and Formaldehyde.
  2. Acetophenone and acetaldehyde.
  3. Benzaldehyde and acetaldehyde.
  4. Benzaldehyde and acetone.
  1. Which of the following will undergo aldol condensation?
  1. $HCHO$
  2. $CH_3CH_2OH$
  3. $C_6H_5CHO$
  4. $CH_3CH_2CHO$
  1. Which of the following does not undergo aldol condensation?
  1. $CH_3CHO$
  2. $CH_3CH_2CHO$
  3. $CH_3COCH_3$
  4. $C_3H_2CHO$
Standard electrode potentials are used for various processes:
  • It is used to measure relative strengths of various oxidants and reductants.
  • It is used to calculate standard cell potential.
  • It is used to predict possible reactions.
A set of half-reactions (in acidic medium) along with their standard reduction potential, $E^\circ ($in volt$)$ values are given below:
$I_2 + 2e^- \rightarrow 2I^- ; E^\circ = 0.54 V$
$Cl_2 + 2e^- \rightarrow 2Cl^- ; E^\circ = 1.36 V$
$Mn^{3+} +e^- \rightarrow Mn^{2+}; E^\circ = 1.50 V$
$Fe^{3+} + e^- \rightarrow Fe^{2+}; E^\circ = 0.77 V$
$O_2 + 4H^+ + 4e^- \rightarrow 2H_2O ; E^\circ = 1.23 V$
The following questions are multiple choice questions. Choose the most appropriate answer:
  1. Which of the following statements is correct?
  1. $Cl^-$ is oxidised by $O_2.$
  2. $Fe^{2+}$ is oxidised by iodine.
  3. $I^-$ is oxidised by chlorine.
  4. $Mn^{2+}$ is oxidised by chlorine.
  1. $Mn^{3+}$ is not stable in acidic medium, while $Fe^{3+}$ is stable because:
  1. $O_2$ oxidises $Mn^{2+}$ to $Mn^{3+}$
  2. $O_2$ oxidises both $Mn^{2+}$ to $Mn^{3+}$ and $Fe^{2+}$ to $Fe^{3+}$
  3. $Fe^{3+}$ oxidises $H_2O$ to $O_2$
  4. $Mn^{3+}$ oxidises $H_2O$ to $O_2$
  1. The strongest reducing agent in the aqueous solution is:
  1. $I^-$
  2. $Cl^-$
  3. $Mn^{2+}$
  4. $Fe^{2+}$
  1. The emf for the following reaction is:
$\text{I}_2+\text{KCl}\rightleftharpoons2\text{KI}+\text{Cl}_2$
  1. $-0.82\ V$
  2. $+0.82\ V$
  3. $-0.73\ V$
  4. $+0.73\ V$
  1. Which of the following statements is correct for the following reaction?
$Fe^{3+} + Mn^{2+} \rightarrow Fe^{2+}+ Mn^{3+}$
  1. The emf of the cell is positive.
  2. $Fe^{3+}$ oxidises $Mn^{2+}.$
  3. The reaction does not occur.
  4. All are correct.

 
Read the passage given below and answer the following questions:
Interhalogen compounds are formed when halogen group elements react with each other. These are the compounds which consist of two or more different elements of group$-17$. A halogen with large size and low electronegativity reacts with an element of group$-17$ with small size and high electronegativity. As the ratio of radius of larger and smaller halogen increases, the number of atoms in a molecule also increases.
The following questions are multiple choice questions. Choose the most appropriate answer:
  1. The stability of interhalogen compounds follows the order.
  1. $IF_3 > BrF_3 > CIF_3$
  2. $CIF_3 > BrF_3 > IF_3$
  3. $BrF_3 > IF_3 > CIF_3$
  4. $CIF_3 > IF_3 > BrF_3$
  1. Identify the correct match from the following.
  1. $[ICI_2]^- - $ bent.
  2. $IF_7 $- pentagonal bipyramidal.
  3. $CIF_3 $- trigonal planar.
  4. $[BrF_4]^-$ - square pyramidal.
  1. In $XA_5$, the central atom has $($both $X$ and $A$ are halogens$).$
  1. $5$ bond pairs and no lone pairs.
  2. $5$ bond pairs and one lone pair.
  3. $6$ bond pairs and no lone pairs.
  4. $4$ bond pairs and one lone pair.
  1. In the known interbalogen compounds, the maximum number of atoms are,
  1. $4$
  2. $5$
  3. $8$
  4. $7$
  1. Which of the following is not the characteristic of interhalogen compounds.
  1. They are more reactive than halogens.
  2. They are quite unstable but none of them is explosive.
  3. They are covalent in nature.
  4. They have low boiling points and are highly volatile.