Question
State Markovnikov’s rule and explain it with the help of an example.

Answer

i. Markovnikov’s rule: When an unsymmetrical reagent is added to an unsymmetrical alkene, the negative part (X-) of the reagent gets attached to the carbon atom which carries less number of hydrogen atoms.
ii. For example, addition of HBr to unsymmetrical alkenes yield two isomeric products.
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iii. Experimentally it has been found that 2-Bromopropane is the major product.

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