MCQ
The average translational energy and the $r.m.s.$ speed of molecules in a sample of oxygen gas at $300 K$ are $6.21 \times {10^{ - 21}}\,J$ and $484\, m/s$ respectively. The corresponding values at $600 K$ are nearly (assuming ideal gas behaviour)
  • A
    $12.42 \times {10^{-21}}\,J,\;968\,m/s$
  • B
    $8.78 \times {10^{-21}}J,\;684\,m/s$
  • C
    $6.21 \times {10^{-21}}\,J,\,968\,m/s$
  • $12.42 \times {10^{-21}}\,J,\;684\,m/s$

Answer

Correct option: D.
$12.42 \times {10^{-21}}\,J,\;684\,m/s$
d
$E \propto T$

$\therefore \frac{{{E_2}}}{{{E_1}}} = \frac{{{T_2}}}{{{T_1}}} = \frac{{600}}{{300}} = 2$

$\therefore \,\,{E_2} = 2{E_1}\,\,\,$

$\therefore \,\,\,{E_2} = 2 \times 6.21 \times {10^{ - 21}}\,\, = 12.42 \times {10^{ - 21}}\,J$

${\upsilon _{rms}} \propto \sqrt T $ પરથી $\frac{{{{({\upsilon _{rms}})}_2}}}{{{{({\upsilon _{rms}})}_1}}} = \sqrt {\frac{{{T_2}}}{{{T_1}}}}  = \,\sqrt {\frac{{600}}{{300}}} \, = \,\sqrt 2 \,\,$

$\therefore {({\upsilon _{rms}})_2}\, = \,\sqrt 2 {({\upsilon _{rms}})_1}$

$\therefore {({\upsilon _{rms}})_2}\,\, = \,\sqrt 2  \times 325\,\, = \,459.6\,m/s$

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