MCQ
The correct $IUPAC$ name for $[CrF_2(en)_2] \,Cl$ is
  • A
    chloro difluorido ethylene diaminechromium $(III)$ chloride
  • difluoridobis (ethylene diamine) chromium $(III)$ chloride
  • C
    difluorobis-(ethylene diamine) chromium $(III)$ chloride
  • D
    chloro difluoridobis (ethylene diamine) chromium $(III)$ (Karnataka )

Answer

Correct option: B.
difluoridobis (ethylene diamine) chromium $(III)$ chloride
b
In $TiF _{6}^{2-}$ titanium is in $+4$ state. In $\mathrm{Cu}_{2} \mathrm{Cl}_{2}$ the copper is in $+1$ state. Thus in both cases, transition from one d-orbital to other is not possible.

$\mathrm{Ti}-3 d^{2} 4 s^{2} \rightarrow \mathrm{Ti}^{4+}-3 d^{0} 4 s^{0}$

$\mathrm{Cu}-3 d^{10} 4 s^{1} \rightarrow \mathrm{Cu}^{+}-3 d^{10} 4 s^{0}$

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