- A$C$ and ${N_2}O$
- B$Cu$ and ${N_2}O$
- C$Na$ and $N{H_3}$
- ✓$Cu$ and $HN{O_3}$
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$\mathrm{A}+\mathrm{B} \underset{\text { Step } 3}{\text { Step } 1} \mathrm{C} \xrightarrow{\text { Step } 2} \mathrm{P}$
Some details of the above reaction are listed below.
| Step |
Rate constant $\left(\sec ^{-1}\right)$ |
Activation energy $\left(\mathrm{kJ} \mathrm{mol}^{-1}\right)$ |
| $1$ | ${k}_1$ | $300$ |
| $2$ | ${k}_2$ | $200$ |
| $3$ | ${k}_3$ | $\mathrm{Ea}_3$ |
If the overall rate constant of the above transformation (k) is given as $\mathrm{k}=\frac{\mathrm{k}_1 \mathrm{k}_2}{\mathrm{k}_3}$ and the overall activation energy $\left(E_2\right)$ is $400 \mathrm{~kJ} \mathrm{~mol}^{-1}$, then the value of $\mathrm{Ea}_3$ is $\qquad$ $\mathrm{kJ} \mathrm{mol}^{-1}$ (nearest integer)
$\left\{ en = H _2 NCH _2 CH _2 NH _2\right.$; atomic numbers: $\left.Ti =22 ; Cr =24 ; Cp =27 ; Pt =78\right\}$
| List-$I$ | List-$II$ |
| $P.$ $\left[ Cr \left( NH _3\right)_4 Cl _2\right) Cl ]$ | $1.$ Paramagnetic and exhibits ionisation isomerism |
| $Q.$ $\left[ Ti \left( H _2 O \right)_5 Cl \right]\left( NO _3\right)_2$ | $2.$ Diamagentic and exhibits cis-trans isomerism |
| $R.$ $\left[ Pt ( en )\left( NH _3\right) Cl \right] NO _3$ | $3.$ Paramagentic and exhibits cis-trans isomerism |
| $S.$ $\left[ Co \left( NH _3\right)_4\left( NO _3\right)_2\right] NO _3$ | $4.$ Diamagentic and exhibits ionisation isomerism |
Codes: $ \quad P \quad Q \quad R \quad S $
