MCQ
To synthesize the unsymmetrical alkyne $C{H_3} - C \equiv C - C{H_2} - C{H_3}$ the reagents needed would be
  • A
    Ethene, iodoethane, iodomethane and potassium hydroxide
  • B
    Acetaldehyde, $1-$bromopropane and conc. ${H_2}S{O_4}$
  • C
    $1, 2-$dichloroethane, $1-$propanol and alcoholic potassium hydroxide
  • Ethyne, iodomethane, iodoethane and sodamide

Answer

Correct option: D.
Ethyne, iodomethane, iodoethane and sodamide
d
(d) $CH\equiv CH\xrightarrow{NaN{{H}_{2}}}CH\equiv {{C}^{-}}N{{a}^{+}}\underset{-NaI}{\mathop{\xrightarrow{C{{H}_{3}}I}}}\,CH\equiv C-C{{H}_{3}}$ 

   $\underset{\text{Pent}-\text{2}-\text{yne}}{\mathop{{{C}_{2}}{{H}_{5}}-C\equiv C-C{{H}_{3}}}}\,\underset{-NaI}{\mathop{\xleftarrow{{{C}_{2}}{{H}_{5}}I}}}\,N{{a}^{+}}\,{{C}^{-}}\equiv C-C{{H}_{3}}$

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